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Influence of Defects on Dielectric Properties of (CH_{3}NH_{3})_{5}Bi_{2}X_{11} (x=Cl, Br) Crystals

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Μróz J., Pykacz H., Jakubas R.
Acta Physica Polonica A
|
1995
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vol. 88
|
issue 2
369-374
EN
Influence of defects on ferroelectric properties of the (CH_{3}ΝΗ_{3})_{5}Bi_{2}Χ_{11} (Χ = Cl, Br) crystals in the vicinity of ferro-paraelectric phase transition was investigated. γ-irradiation of both crystals insignificantly shifts Tc towards higher temperature. The substitution of chlorine atoms by iodine ones in the (CH_{3}ΝΗ_{3})_{5}Bi_{2}Cl_{11} crystal drastically reduces the magnitude of the dielectric permittivity but does not influence on the temperature behaviour of the spontaneous polarization.
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