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vol. 125
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issue 2
313-315
EN
The aim of this study was to analyze the influence of various luting materials and surface treatments on adhesive strength for zirconia ceramics and luting cements. The zirconia framework specimens were made into cylinders. Prior to cement, zirconia framework specimens underwent various surface treatments (sandblasting with 110 μm Al_2O_3 particles, milling with 240-grift silicon sand paper and silanization). Resin luting cement and glass ionomer luting cement were then applied on the surface of zirconia specimens. The specimens were then subjected to a shear force. The fractured surfaces were visually analyzed by scanning electron microscopy. The shear bond strength values of resin luting cement bonded to zirconia specimens were significantly higher than glass ionomer luting cement bonded to zirconia specimens (P < 0.05). The shear bond strength values of zirconia specimens sandblasted with 110 μm Al_2O_3 particles were significantly higher than those milled with silicon carbide papers and underwent silanization (P < 0.05). The shear bond strength values of zirconia specimens milled with silicon carbide papers and underwent silanization were not significantly different (P < 0.05). The highest shear bond strength values were achieved when the zirconia specimens were sandblasted and bonded to resin luting cement. Airborne-particle abrasion was an effective method which could enhance the bond strength of zirconia ceramics and cements. The resin luting cement exhibited a higher bond to zirconia than glass ionomer luting cement.
EN
Molecular dynamics simulations with condensed-phase optimized molecular potentials for atomistic simulation studies force field are performed to investigate the structure, equation of state, and mechanical properties of high energetic material pentaerythritol tetranitrate. The equilibrium structural parameters, pressure-volume relationship and elastic constants at ambient conditions agree excellently with experiments. In addition, fitting the pressure-volume data to the Birch-Murnaghan or Murnaghan equation of state, the bulk modulus B₀ and its first pressure derivative B'₀ are obtained. Moreover, the elastic constants are calculated in the pressure range of 0-10 GPa at room temperature and in the temperature range of 200-400 K at the standard pressure, respectively. By the Voigt-Reuss-Hill approximation, the mechanical properties such as bulk modulus B, shear modulus G, and the Young modulus E are also obtained successfully. The predicted physical properties under temperature and pressure can provide powerful guidelines for the engineering application and further experimental investigations.
EN
The spin resonance of excess electrons is observed with the detection either on the neutral or the negatively charged exciton X^{-} emission in type I CdTe/(Cd,Mg)Te quantum wells with excess electrons of low density. It is found that the electron spin-dependent and electron spin-conserving formation and recombination of X^{-} make the optical detection of the spin resonance of excess electrons feasible. For the first time, optically detected magnetic resonance is used to study fast optical transition processes in the nanosecond timescale where the microwave-induced magnetic transition rate is much lower than the optical transition rate.
EN
Novel nanometer scale structures have been produced by thermal heating or laser irradiation on the surface of single- and multi-layers of C_{60} and C_{84} on Si. These structures were examined by combined measurements of scanning tunneling spectroscopy and high resolution electron energy loss spectroscopy. The results show specific chemical reactions of substrate with carbon clusters having single- and double-bonded network. Covalent bonds are formed in some of these chemical reactions.
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