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Synthesis and Structure Characterisation of Micro-and Nanocrystalline Powders of Dy_{1-x}R_xFeO₃ (R = La, Pr, Nd, Sm, Gd)

100%

Pavlovska O., Lutsyuk I., Kondyr A., Zhydachevskyy Y., Vakhula Y., Pieniążek A., Vasylechko L.

Acta Physica Polonica A

2018

vol. 133

issue 4

802-805

This work deals with the study of the phase and crystal structure behaviour of new micro- and nanocrystalline ferrites Dy_{1-x}R_xFeO₃ obtained by solid state reactions (R = La, Pr) and sol-gel citrate (R = Nd, Sm, Gd) techniques. It was established that all synthesized samples adopt orthorhombic perovskite structure isotypic with GdFeO₃. Unit cell dimensions and atomic coordinates of the mixed rare earth ferrites derived by full profile Rietveld refinement technique agree well with the data of the "pure" DyFeO₃ and RFeO₃ compounds, thus proving formation of continuous solid solutions Dy_{1-x}R_xFeO₃ in the DyFeO₃-RFeO₃ systems (R = La, Pr, Nd, Sm, Gd). Peculiarity of the Dy_{1-x}La_xFeO₃ series is the lattice parameters crossover and formation of dimensionally tetragonal structure at x ≈0.97.

Investigation of Co Ions Diffusion in Gd₃Ga₅O₁₂ Single Crystals

68%

Sugak D., Syvorotka I., Yakhnevych U., Buryy O., Vakiv M., Ubizskii S., Włodarczyk D., Zhydachevskyy Y., Pieniążek A., Jakiela R., Suchocki A.

Acta Physica Polonica A

2018

vol. 133

issue 4

959-964

Spatial changes of properties of Gd₃Ga₅O₁₂ (GGG) single crystals caused by diffusion of cobalt ions during high-temperature annealing (1200°C, 24 h) in Co₃O₄ powder are investigated. The registration of these changes was carried out by optical spectrophotometry, microscopy and micro-Raman scattering methods. Changes in structure of near-surface layers of the crystal were investigated by X-ray diffraction technique. It was shown that the additional absorption induced by annealing is related to intra-center optical transitions in Co²⁺ ions, which occupy tetrahedral positions in the garnet structure at the distances of 250-500 μm from the crystal surface. The dependence of induced absorption with depth has got a non-monotonous character with a maximum at 400 μm. A comparison of the results obtained by different methods allows to suppose that the thermal treatment of GGG in the presence of cobalt ions leads to formation of the structurally and chemically non-uniform layer with a width about 500 μm.

Magnetic and Structural Studies of GeMnSnTe Epitaxial Layers

68%

Grochot A., Knoff W., Taliashvili B., Wołkanowicz W., Minikayev R., Pieniążek A., Łusakowska E., Sawicki M., Jantsch W., Story T., Przybylińska H.

Acta Physica Polonica A

2017

vol. 132

issue 2

340-342

MBE grown Ge_{1-x-y}Mn_xSn_yTe layers with Mn content ranging from 10 to 30% and Sn content ranging from 2 to 5% have been characterized with X-ray diffraction, energy-dispersive X-Ray spectroscopy, atomic force microscopy, SQUID magnetometry, and ferromagnetic resonance. All layers (except the one with the highest Mn and Sn content) were found to be single phase rhombohedral, with the distortion axis perpendicular to the layer surface, and ferromagnetic. Ferromagnetic resonance studies have shown that co-doping with a few percent of tin makes the lattice more rigid and changes considerably the magnetocrystalline anisotropy, from purely uniaxial in GeMnTe to distorted cubic in Ge_{1-x-y}Mn_xSn_yTe at the same Mn content.

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3 Acta Physica Polonica A

2 2018

1 2017

3 Pieniążek A.

2 Zhydachevskyy Y.

1 Buryy O.

1 Grochot A.

1 Jakiela R.

1 Jantsch W.

1 Knoff W.

1 Kondyr A.

1 Lutsyuk I.

1 Minikayev R.

1 Pavlovska O.

1 Przybylińska H.

1 Sawicki M.

1 Story T.

1 Suchocki A.

1 Sugak D.

1 Syvorotka I.

1 Taliashvili B.

1 Ubizskii S.

1 Vakhula Y.

1 Vakiv M.

1 Vasylechko L.

1 Wołkanowicz W.

1 Włodarczyk D.

1 Yakhnevych U.

1 Łusakowska E.

Search results

Synthesis and Structure Characterisation of Micro-and Nanocrystalline Powders of Dy_{1-x}R_xFeO₃ (R = La, Pr, Nd, Sm, Gd)

Investigation of Co Ions Diffusion in Gd₃Ga₅O₁₂ Single Crystals

Magnetic and Structural Studies of GeMnSnTe Epitaxial Layers