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d and f Electrons in a qp-Quantized Cubical Field

100%

Kibler M., Sztucki J.

A procedure for qp-quantizing a crystal-field potential V with an arbitrary symmetry G is developed. Such a procedure is applied to the case where V involves cubic components (G = 0) of the degrees 4 and 6. This case corresponds to d and f electrons in a qp-quantized cubical potential. It is shown that the qp-quantization of the considered cubical potential is equivalent to a symmetry breaking of type O → D_{4}. A general conjecture about this symmetry breaking phenomenon is given.

Stereoselectivity Effect on Tb(III)-Eu(III) Energy Transfer in Complexes with Glutamic Acid and Alanine

71%

Legendziewicz J., Huskowska E., Stręk W., Łukowiak E., Sztucki J.

Acta Physica Polonica A

1993

vol. 84

issue 5

1021-1024

The effect of stereoselectivity on energy transfer between Tb(III) and Eu(III) in crystals with glutamic acid and alanine was investigated. It was found that the stereoselectivity significantly changes the energy transfer in these systems. The theoretical model for the selective dependent energy transfer processes in lanthanide systems is developed and the nature of processes occurring in both systems under investigation briefly discussed.

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2 Acta Physica Polonica A

2 1993

2 Sztucki J.

1 Huskowska E.

1 Kibler M.

1 Legendziewicz J.

1 Stręk W.

1 Łukowiak E.

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d and f Electrons in a qp-Quantized Cubical Field

Stereoselectivity Effect on Tb(III)-Eu(III) Energy Transfer in Complexes with Glutamic Acid and Alanine