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Electrical resistance, transversal magnetoresistance and the Hall effect were studied on polycrystalline CaTi_xRu_{1-x}O_3 (x=0, 0.07) samples using a conventional Quantum Design PPMS-9 equipment in the temperature range 2-300 K and magnetic field up to 9 T. Substantial differences were found between the two samples: (i) opposite to the metallic character of CaRuO_3, the substituted sample has insulating-like electrical resistance;(ii) the magnetoresistance of the substituted sample changes the sign from negative to positive values with increasing temperature. The magnetoresistance of CaRuO_3 is negative, the sign reversal is induced by magnetic field and only at temperatures below 15 K, such a behaviour is predicted for clustered systems;(iii) the Hall voltage in pure CaRuO_3 also changes sign from negative to positive values above 35 K. This temperature coincides with the observed magnetic transition temperature, indicating that the magnetic state and the carrier character interrelate.
EN
The influence of Ti substitution on the specific heat of the CaTi_xRu_{1-x}O_3 system at low concentrations x=0, 0.005, and 0.03 was studied in the temperature range of 2-300 K at magnetic fields up to 9 T. Small peak was revealed in the C/T vs. T^2 dependence at around 3 K, which are field sensitive (the electronic specific heat coefficient γlinearly decreases with the increase in magnetic field), and might be connected to some kind of magnetic ordering. The coefficient γis suppressed also by Ti substitution.
EN
We present a comparative study of Na_{0.7}CoO_2 samples obtained from three different sources and prepared by different methods. The specific heat and magnetic susceptibility measurements in the temperature range 2-300 K show substantial influence on the observed anomalies, which underlines that the system is extremely sensitive to preparation protocols.
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