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A model of the meat waste management

100%
Kowalski Z., Krupa-Żuczek K.
Polish Journal of Chemical Technology
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2007
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vol. 9
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issue 4
91-97
EN
The European Union produces about 18 million tons of waste from meat industry per year. The real danger of the BSE disease caused a necessity of looking for a new alternative solution of meat waste management. The proposed solution of meat industry waste management would create meat production waste free with the use of the cleaner production method. Cleaner production includes: pollution prevention, reduction of the source, recovery of materials and energy (for example: the recovery of blood plasma and protein hydrolisate from bone sludge) and their recycling. The thermal processing of meat industrial waste (bone sludge, meat-bone meal and odour) is anticipated, too. Ashes from meat calcining have the phosphorus content close to its concentration, of the typical phosphoric raw materials. That confirmed the possibility of using such ashes as the substitute of phosphoric raw materials. The target model of waste free meat waste management included the results of the implemented and current research.
2
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Thermal utilization of mixtures of bone waste

81%
Staroń P., Kowalski Z., Krupa-Żuczek K., Wzorek Z.
Polish Journal of Chemical Technology
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2010
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vol. 12
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issue 4
26-30
EN
The results of a research related to the physico - chemical properties of the mixture of bone - waste and their ingredients have been presented. The mixtures was made up from waste: bovine bones, pork bones, bone sludge and bone meal. The content of the individual waste in the mixtures was selected on the basis of the heat of the combustion of the mixture and the amount of the waste produced in a meat processing plant. The heat of the combustion has been determined by the calorimeter, the content of phosphorus by spectrophotometric method, calcium by titration and phase composition by X - ray diffraction.The investigations confirmed that pork bones have the highest heat of the combustion 17 MJ/kg because of a big amount of fats. The analyzed waste has contained on average 16.5 wt % phosphorus and above 30 wt % calcium. X - ray diffraction method has proved that in bone waste one phase - hydroxyapatite occurs.
3
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Manufacturing of phosphoric acid from hydroxyapatite, contained in the ashes of the incinerated meat-bone wastes

81%
Krupa-Żuczek K., Kowalski Z., Wzorek Z.
Polish Journal of Chemical Technology
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2008
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vol. 10
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issue 3
13-20
EN
The results of the investigations concerning phosphoric acid manufacturing, by the extraction method, from the ashes containing hydroxyapatite, obtained through the thermal treatment of bone sludge have been presented. The incinerated bone sludge with ~ 16% P content and the minimal amount of impurities can be an alternative source for phosphoric acid production. The process consists in two stages. In the 1st stage, reaction of hydroxyapatite with phosphoric acid resulting in monocalcium phosphate formation in the solution obtained is carried out. The tests revealed that overall hydroxyapatite dissolution in phosphoric acid takes place when the concentration is 37% H3PO4. In the 2nd stage monocalcium phosphate is converted into calcium sulphate using concentrated sulphuric acid at the recommended temperature of 95°C. The principles of the technological idea of the process of phosphoric acid manufacturing from HA-containing ashes, obtained by bone wastes incineration, as well as a preliminary economic analysis for the production of 10 000 t/year of food-grade phosphoric acid have been developed.
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