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Chirality Induced by Magnetoelectrolysis

100%
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vol. 126
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issue 1
380-381
EN
Surface chiral formation of Cu films was investigated in the galvanostatic electrodeposition under a magnetic field of 5 T perpendicular to the electrode surface. The surface chirality was examined by electrochemical voltammograms of a chiral molecule of tartaric acid. The chiral induction depended on the magnetoelectrodeposition time, and this implied that the formation of the self-organized state of magnetohydrodynamic flows around the electrode is crucial for the chiral formation.
2
64%
EN
The chiral activities of electrodeposited surfaces fabricated under vertical magnetic fields were theoretically examined. Chiral activities arise from the micro-vortexes, called micro-MHD (magnetohydrodynamic) flows (MMF), activated under a tornado-like vortex called vertical MHD flow (VMF). It was concluded that the interaction between MMF and VMF determines the activities.
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