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Controlled free radical polymerization of methacrylates containG carbazole and cumarin pendant groups

100%
Pisarek U., Galica M.
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PL
This paper presents the results of synthesis copolymers based on 2-(9-carbazolyl)ethyl methacrylate (CEM) and 7- (diethylamino)coumarin-3-carboxylic acid 2-(methacryloyloxy) ethyl ester (MK) using ATRP technique. The reactions were carried out both under conventional and microwave conditions. Various activations system with organic ligand 1,10-phenanthroline monohydrate were tested. Obtained polymers were characterized by GPC and UV-VIS techniques.
2
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Aggregation-induced emission enhancement of optically active copolymers

100%
Galica M., Bogdał D.
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PL
The absorption and photoluminescence spectra of the polymer in DMF-H2O systems were analyzed. Finally, it was determined to enhance the ability of AIEE effect for CEM-5MK solutions. In results, study confirmed the usefulness of the copolymers CEM / MK as materials for optoelectronic applications.
3
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Application of a carbazole derivative as a spectroscopic fluorescent probe for real time monitoring of cationic photopolymerization

81%
Ortyl J., Galica M., Popielarz R., Bogdał D.
Polish Journal of Chemical Technology
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2014
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vol. 16
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issue 1
75-80
EN
The performance of 1-(9-ethylcarbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione (1) as a fluorescent probe for the monitoring of cationic photopolymerization processes by Fluorescence Probe Technique (FPT) has been evaluated in comparison with the response of 7-diethylamino-4-methylcoumarin (Coumarin 1) (2). Triethylene glycol divinyl ether and diphenyliodonium hexafluorophosphate were used as an example monomer and a cationic photoinitiator respectively. It has been found that the probe 1 withstands the cationic polymerization conditions and provides correct probe response. 1-(9-ethylcarbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione shifts its fluorescence spectrum with progress of cationic photopolymerization of the monomer, which enables the monitoring of the polymerization progress using the fluorescence intensity ratio measured at two different wavelengths as the progress indicator. By comparing the behavior of 1 and 2, it has been documented that the fluorescence spectrum of probe 1 shows a spectacular hypsochromic shift (Δλ = 33 nm) upon the monomer polymerization, while the shift of 2 is three times smaller (Δλ = 11 nm). Moreover, the sensitivity of probe 1 is more than 2.5-times higher than that of any other probes suitable for monitoring cationic polymerization processes, reported previously. Therefore, application of the carbazole derivative (1) as a new probe for the monitoring of the crosslinking process of coatings cured by cationic photopolymerization has been proposed.
4
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Application of Na12[WZn3(H2O)2][ZnW9O34)2] polyoxometalate as a catalyst in oxidation of alcohols under microwave irradiation

81%
Kasprzyk W., Galica M., Bednarz S., Bogdał D.
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PL
In this paper the results of oxidation of alcohols under microwave irradiation using Na12[WZn3(H2O)2][ZnW9O32)2] (ZnPOM) as a catalyst was shown. These reactions were conducted in microwave high-pressure reactor using acetonitryl as organic solvent and 30% hydrogen peroxide as oxidant. Under reaction conditions primary alcohols were oxidized to appropriate acids, secondary alcohols were oxidized to ketones. In case of diols it was found that secondary –OH groups were oxidized in the first instance.
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