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EN
The results of X-ray diffraction studies on structural changes in the near-surface layers in the NiTi alloy caused by nitrogen-ion implantation with the energy E = 50 keV and the fluence D = 10^{18} cm^{-2} are presented. X-ray diffractometry, using the Philips diffractometer type X'Pert in the Bragg-Brentano geometry, was used to identify the phase composition of NiTi alloy. For layer by layer analysis of structural changes in the near-surface layers, the D8 Discover Bruker diffractometer with polycapilar beam optics was used. The ion-implanted NiTi alloy in the near-surface layer exhibits five phases: the dominating austenite phase, two martensitic phases and a small amount of the Ni_4Ti_3 and NTi phases. Along with the decreasing thickness of the near-surface layer investigated in material an increasing fraction of the Ni_4Ti_3 and NTi phases was observed. With the thickness of this layer about 340 nm, besides still existing the austenite, Ni_4Ti_3 and NTi phases, only one martensitic phase is present in the alloy. Further decrease of the thickness of the near-surface layer to about 170 nm leads to the increasing fraction of the Ni_4Ti_3 and NTi phases.
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