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Magnetic Properties of Transition Metal Molybdates

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Konieczny P., Pełka R., Grzesiak-Nowak M., Szymańska A., Łasocha W., Wasiutyński T.
Acta Physica Polonica A
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2014
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vol. 126
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issue 1
250-251
EN
Two examples of transition metal molybdates were studied with the use of X-ray diffraction and DC magnetometry techniques. First compound, copper dimolybdate trihydrate CuMo_{2}O_{7}·3H_{2}O contains 2D layers. The second one is fibrillar cobalt trimolybdate octahydrate CoMo_{3}O_{10}·8H_{2}O. Both compounds exhibit paramagnetic behaviour at room temperature. However, in the first one copper ions form dimers linked by oxygen bridges, in which exchange interactions between two localized spin states occur. The second compound consists of isolated cobalt ions in the octahedral surroundings, resulting in magnetic properties deviating from the Curie law.
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