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Optical absorption in PECVD deposited thin hydrogenated silicon in light of ordering effects

100%
Müllerová J., Vavruňková V., Šutta P.
Open Physics
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2009
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vol. 7
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issue 2
315-320
EN
We report results obtained from measurements of optical transmittance spectra carried out on a series of silicon thin films deposited by plasma-enhanced chemical vapour deposition (PECVD) from silane diluted with hydrogen. Hydrogen dilution of silane results in an inhomogeneous growth during which the material evolves from amorphous hydrogenated silicon (a-Si:H) to microcrystalline hydrogenated silicon (µc-Si:H). Spectral refractive indices and absorption coefficients were determined from transmittance spectra. The spectral absorption coefficients were used to determine the Tauc optical band gap energy, the B factor of the Tauc plots, E 04 (energy at which the absorption coefficient is equal to 104 cm−1), and the Urbach energy as a function of the hydrogen dilution. The results were correlated with microstructure, namely volume fractions of the amorphous and crystalline phase with voids, and with the grain size.
2
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Spectral properties and photophysics of arylacetylenes in thin films

100%
Flamini R., Carlotti B., Spalletti A., Marrocchi A.
Organic Photonics and Photovoltaics
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2014
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vol. 2
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issue 1
EN
We report the photobehaviour of a series of eight structurally related arylacetylene derivatives, in solution as well as in pristine and PC61BM blended thin-_lms. The formation of both H- and J-aggregates in the solid state have been demonstrated, and, interestingly, an energy transfer from H-aggregates or/and from residual "unstacked" molecules to J-aggregates has been found, the latter being the only emitting species. The fuorescence quenching by PC61BM at di_erent loadings has been studied in blend films, and it has been found particularly effcient in the case of a symmetrical peripheral substitution of the acetylene derivative core. Preliminary time-resolved measurements in emission (ns resolution) and in absorption (fs resolution) con_rmed the H⟶J energy transfer and underlined the presence of delayed fuorescence from Jaggregates, formed by energy transfer from the long-lived first excited singlet state of H-aggregates. In all cases, a homogeneous surface morphology of thin films.
3
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Absorption of Twisted and Linearly Polarized Light in Graphene with Rashba Spin-Orbit Interaction

100%
Inglot M., Dugaev V.
Acta Physica Polonica A
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2017
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vol. 132
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issue 1
193-195
EN
Theoretical analysis of the electron excitations in graphene on substrate by twisted, linear and circular polarization light is presented. We use a model of graphene with constant Rashba spin-orbit interaction. In this case, the band structure of electrons includes four energy bands. The main objective of this work is to compare light absorptions in graphene for different kinds of light, namely, twisted (with nonzero orbital angular momentum) and linear polarized light. The orbital angular momentum light is characterized by some parameters q and l, which can modify the response, while for the linear polarization, the absorption is modified only in the region determined by the Rashba spin-orbit coupling α.
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