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EN
We calculated in this study the Raman frequencies of some lattice modes in the melting region of ammonia solid I. The Raman frequencies of those phonon modes were obtained through the Grüneisen relation using the volume data for the ammonia solid I from the literature. Our calculated Raman frequencies require for comparison the experimental Raman frequencies measured as a function of pressure for some fixed temperatures in the ammonia solid I.
EN
The pressure dependence of the Raman frequencies for the ν_{21} mode is studied by using the volume data at room temperature close to the transitions among the phases of III, IV and V in cyclohexane. By determining the pressure dependence of the mode Grüneisen parameter γ_{T} in the phases and taking the average values, the Raman frequencies of those modes associated with the phase transitions are predicted through the volume data in cyclohexane. Our predicted Raman frequencies agree with those observed experimentally in this organic molecule. The Raman frequencies of the other modes can be calculated in cyclohexane and also in some molecular crystals using the method given here.
EN
The pressure dependence of the Raman linewidths for the ν_1 breathing mode is analyzed using the experimental data from the literature for the solid phases (I, II, III and III') in benzene. Increase (I, III and III') and decrease (II) in the Raman linewidths are described by a power-law analysis with the critical exponent β. The β values we find, which characterize the phase transition are in favour of the first order among those phases considered in benzene. The temperature and pressure dependence of the frequencies and linewidths of various Raman modes can be analyzed using a power-law formula, as studied here for the solid phases (I, II, III and III') in benzene when the experimental data are available in the literature.
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