Technological problems of natural gas desulfurization in syngases manufacturing plants have been discussed and the results of investigations on the activity of the model Ni-Mo/Al2O3 catalyst in hydrogenation of selected sulfur compounds have been presented. The HDS reaction rate is dependent on a compound structure. The hydrogenation rate on the Ni-Mo/Al2O3 catalyst for the given sulfur compound increases in the order: CS2(CH3)2S>C4H10S>C2H6S2C4H4S.
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