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2009
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vol. 64
1-10
EN
Amino-, thiol-, urea-, and acethoxy- functionalized polysilsesquioxane xerogels have been obtained by co-condensation of 1,2-bis(triethoxysilyl)ethane with trifunctional silanes. The structural and chemical characterization of the xerogels was done by means of IR, 13C NMR, 29Si NMR spectroscopy, AFM, elemental analysis and nitrogen adsorption measurements. The resulting xerogels have a porous structure (SBET in the range 500-800 m2/g) and a high content of functional groups (2.3-2.7 mmol/g). Majority of these groups are accessible on the surface generating specific adsorption sites. The nature of the functional group introduced by co-condensation substantially influences the porous structure - the resulting samples can be microporous or mesoporous depending on the type of the group used.
EN
In a field emission tube with two probe-holes the cross-correlation functions of current fluctuations from potassium submonolayers on tungsten have been investigated. The measurements were carried out in the temperature range of 290-430 K and with coverages between 0.05 and 0.87. The experimental correlation curves were approximated by a sum of three exponential functions revealing three components with different time constants τ_{i} and amplitudes R. The temperature dependence of the amplitudes R_{2} and R_{3} is discussed in terms of collective flip-flop processes.
3
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FT-IR/PAS Studies of Lunar Regolith Samples

81%
EN
This paper describes investigations of the surface properties of lunar regolith powder samples from the Apollo 11, 12, and 16 missions, respectively. For this part of studies conducted at the Faculty of Chemistry, Maria Curie-Skłodowska University a Fourier transform infrared photoacoustic spectroscopy was applied.
4
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Energy & climate

81%
EN
Based on published reports a short survey is presented on climatic change. Considering world's increase in temperature the use of fossil energy should be replaced as far and as quickly as possible by alternatives. Actual methods for energy production are discussed. At present, only nuclear power plants and concentrating solar power plants are able to meet the large requirements. Regarding the limited resources of nuclear fuel, costs and problems of nuclear techniques urgently solar techniques should be developed for an extended application.
9
37%
EN
We investigated three lunar regolith powder samples from the Apollo missions. Apollo 11 and Apollo 12 samples come from lunar maria and Apollo 16 sample from a highland region. In the present paper we summarise in brief results of measurements using photoelectron spectroscopy (XPS), micro-Raman spectroscopy (RM), x-ray diffraction (XRD), x-ray fluorescence spectroscopy (XRF), temperature programmed reduction and oxidation (TPRO), thermogravimetry (TG), differential thermal analysis (DTA) and nitrogen adsorption. Parts of samples are visualised by means of scanning electron microscopy (SEM/EDX) and atomic force microscopy (AFM).
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