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EN
The magnetic properties of the novel dimeric compound [Cu(H₂O)(OH)(tmen)]₂[Pd(CN)₄]·2H₂O (tmen=N,N,N',N'-tetramethylethylenediamine) with modulated crystal structure were studied in the temperature range from 95 mK to 300 K. Magnetic measurements revealed a presence of weak antiferromagnetic exchange coupling in the compound. The temperature dependence of specific heat is characterized by the presence of a Schottky-like maximum at 0.47 K and a λ-anomaly at 0.28 K, indicating the formation of long-range order in the system. The comparison of the experimental data with theoretical predictions revealed the presence of antiferromagnetic intradimer exchange coupling J/k_{B}= -1.2 K and interdimer coupling of a similar strength mediated via hydrogen bonds between dimeric units forming a frustrated magnetic zig-zag chain structure.
EN
The spin dynamics of a layered magnetic insulator, KEr(MoO₄)₂, have been investigated in a magnetic field applied along the easy axis at temperatures where the magnetism is dominated by the occupation of a ground doublet. More specifically, the DC magnetization and AC susceptibility were studied in magnetic fields up to 5 T and at temperatures ranging from 1.8 to 20 K. The temperature dependence of the AC susceptibility suggests a slowing down of magnetic relaxation with increasing magnetic field. The magnetic field dependence of the AC susceptibility, studied at nominally 2 K, indicates the presence of low-field, intermediate-field, and high-field regimes characterized by the interplay of internal and external magnetic fields that give rise to different relaxation processes.
EN
The influence of pressure on the low-dimensional molecular magnet Cu(H₂O)₂(en)SO₄ (en = ethylenediamine = C₂H₈N₂) has theoretically been shown to affect the exchange interactions of the material. Herein, the results of an experimental study of hydrostatic pressure effects on the temperature dependence of the magnetization are reported. Using two different pressure cells, the magnetization measurements were performed between 2 K and 9.6 K with pressures ranging from ambient to 5.0 GPa. The data preliminarily suggest the presence of a shift in the magnetization peak of the material at the lowest temperatures and at the highest applied pressures. These data serve as a guide for future experimental work employing pressure to study this intriguing system.
EN
The heat transport in a single-crystal of CsNiF_3 has been performed in the temperature range from 2 K to 7 K in a zero magnetic field, B = 0, as well as in sufficiently large magnetic fields, B = 6 T and 9 T, inducing the ferromagnetic ground state along the hard c-axis. CsNiF_3 represents an S = 1 quasi-one-dimensional XY ferromagnet with the intra-chain exchange coupling J/k_{B} ≈ 24 K, single-ion anisotropy D/k_{B} ≈ 8 K, and ordering temperature T_{N} = 2.7 K. Comparison of the phonon and magnon velocities suggests that phonons are the main heat carriers in this magnetic insulator. The thermal conductivity in B = 0 was analysed in the frame of a standard Debye model. The temperature dependence of the effective phonon mean free path was calculated from the experimental data, and the enhancement of the phonon mean free path in B ≠ 0 was obtained, indicating that magnons act as scattering centers for phonons.
EN
Magnetic susceptibility and X-band electron spin resonance study of a two-dimensional Heisenberg antiferromagnetic system CuBr_2(bipy), where bipy = C_{10}H_8N_2 is 4,4'-bipyridyl, has been performed in the temperature range from 300 K down to 2 K. A rhombic anisotropy of the g-factor was obtained from X-band EPR measurements with g_{x} = 2.037, g_{y} = 2.100 and g_{z} = 2.219. The temperature dependence of the magnetic susceptibility with a round maximum observed at 28 K suggests antiferromagnetic type of short-range order. No signature of the magnetic long-range order in studied compound was observed. The comparison of the magnetic susceptibility data with a two-dimensional rectangular Heisenberg model yields the values of intralayer exchange couplings J/k_{B} = - 47 K and J'/k_{B} = - 9.4 K.
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EN
The low temperature magnetic response of Mn(III)F(salen), salen = H_{14}C_{16}N_{2}O_{2}, an S=2 linear-chain system, has been studied. Using a single crystal with the field applied perpendicular to the chain direction, torque magnetometry, down to 20 mK and up to 18 T, revealed a feature at 3.8 T when T ≤ 400 mK. ESR ( ≈200 GHz) studies, using single crystals at 4 K and in 5 T, have not detected any signal. In 10 mT, the temperature dependence of the susceptibility of powder-like samples can be reasonably fit when J/k_{B}=50 K and g=2. In addition, these data are unchanged for P ≤1.0 GPa. Using a randomly-oriented, powder-like, deuterated (12 of 14 H replaced by D) sample of 2.2 g at 270 mK, neutron scattering data, acquired with the Cold Neutron Chopper Spectrometer at the Spallation Neutron Source, show several well defined excitations that may be from the zero-field energy levels of antiferromagnetic S=2 spins with g=2, J/k_{B}=50 K, D/k_{B}=2.8 K, and E/k_{B}=0.5 K.
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