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Determination of p-nitroaniline by the tartrate-acetone-Mn2+-KBrO3-H2SO4 double organic substrate oscillating system using non-equilibrium stationary state

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Gao J., Liu J., Ren J., Niu X., Zhang Y., Yang W.

Open Chemistry

2009

vol. 7

issue 3

298-302

This paper described the determination of p-nitroaniline in a double organic substrate oscillating system of tartrate-acetone-Mn2+-KBrO3-H2SO4. Under the optimum conditions, temperature was chosen as a control parameter to design the bifurcation point and proposed a convenient method for determination of p-nitroaniline. Results showed that the system consisting of 3.5 mL 0.06 mol L−1 tartrate, 4.0 mL 0.7 mol L−1 H2SO4, 1.5 mL 1.5×10−4 mol L−1 MnSO4, 4.0 mL 0.4 mol L−1 acetone and 7.0 mL 0.05 mol L−1 KBrO3 was very sensitive to the surrounding at 33.5°C. A good linear relationship between the potential difference and the negative logarithm concentration of p-nitroaniline was obtained to be in the range of 2.50×10−7∼3.75×10−5 mol L−1 with a lower detection limit of 2.50×10−8 mol L−1. [...]

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1 Open Chemistry

1 2009

1 Gao J.

1 Liu J.

1 Niu X.

1 Ren J.

1 Yang W.

1 Zhang Y.

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Determination of p-nitroaniline by the tartrate-acetone-Mn2+-KBrO3-H2SO4 double organic substrate oscillating system using non-equilibrium stationary state