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Spectral Investigations of Fullerene-Porphyrin Complexes

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Barszcz B., Bogucki A., Laskowska B., Ion R., Graja A.
Acta Physica Polonica A
|
2007
|
vol. 112
|
issue S
S-143-S-152
EN
Spectral investigations of someμ-oxo-dimer complexes of trivalent metals (Mn, Fe) with two different ligands: tetraphenylporphyrin and tetranaphthylporphyrin (TNP), and fullerene (C_{60} and C_{70}) complexes withμ-oxobis[5,10,15,20-tetraarylporphyrinatometal (III)] (TXP-M)_2O dimer, where M = Fe, Mn and X = phenyl or naphthyl, are presented. Discussion of the main electronic and vibrational bands observed in the UV-Vis-IR and Raman spectra of both classes of fullerene-porphyrin systems is given. Experimental data are completed with the quantum chemical calculations of MnTNP^+ component.
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