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Reakcja fentona

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PL
Toksyczność żelaza jest uwarunkowana reakcją Fentona czyli tworzeniem rodników hydroksylowych w reakcji z nadtlenkiem wodoru. Artykuł przedstawia skrótowo historię odkrycia Fentona, kontrowersję dotyczącą natury reaktywnego oksydanta tworzonego w reakcji Fentona, reaktywność rodnika hydroksylowego, udział jonów innych metali w reakcji Fentona i wykorzystanie reakcji Fentona do oczyszczania ścieków.
EN
The toxicity of iron is mainly due to the Fenton reaction i. e. formation of hydroxyl radicals in a reaction with hydrogen peroxide. The paper presents briefly the history of Fenton discovery, the controversy regarding the nature of the reactive oxidant formed in the Fenton reaction, the reactivity of the hydroxyl radical, participation of other metal ions in the Fenton reaction and the application of the Fenton reaction for wastewater treatment.
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2017
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vol. 64
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issue 1
195-198
EN
Deoxyribose test has been widely used for determination of reactivities of various compounds for the hydroxyl radical. The test is based on the formation of hydroxyl radical by Fe2+ complex in the Fenton reaction. We propose a modification of the deoxyribose test to detect strong iron binding, inhibiting participation of Fe2+ in the Fenton reaction, on the basis of examination of concentration dependence of deoxyribose degradation on Fe2+ concentration, at a constant concentration of a chelating agent.
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