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THE INFLUENCE OF SALINITY ON REACTIVE BLACK 5 DYE SORPTION EFFICIENCY ON HYDROGEL CHITOSAN SORBENTS

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Jóźwiak T., Filipkowska U., Bolozan L., Gache L.

Progress on Chemistry and Application of Chitin and its Derivatives

2019

vol. 24

49 - 60

This study examined the effect of salt concentration (NaCl/Na2SO4) on the sorption efficiency of Reactive Black 5 (RB5) dye on chitosan hydrogel granules (CHs). The tested salt concentration was in the range of 0.0 to 0.5 mol/L. The scope of the research included the effect of salinity on RB5 sorption at different pH values (4–11), equilibrium time, and maximum sorption capacity (Langmuir 2 model). At low pH (pH 4, pHpHPZC), an opposite trend was observed (the sorption efficiency of RB5 on CHs increased with increasing salinity). The concentration of salt in the solution did not have a major impact on the equilibrium time of sorption, which depended mainly on the initial pH of the solution (and ranged from 36 to 60 h). The relatively long sorption time resulted from the hydrogel structure of the sorbent used, which slowed the dye absorption ability. The maximum sorption capacity of CHs in relation to RB5 at the optimum pH (pH 4) in the solution without the addition of salt determined after 60 h of sorption was 1.386 mmol RB5/g (1373.5 mg RB5/g). Under conditions of high salinity (0.5 mol Na2SO4/L), at pH 4, the capacity was 17.2% lower (1.148 mmol RB5/g to 1139.7 mg RB5/g), and at pH 11, it was 6.3% higher (1.474 mmol RB5/g to 1460.7 mg RB5/g).

THE INFLUENCE OF CHITOSAN CONTENT IN HYDROGEL BEADS ON THE SORPTION EFFECTIVENESS OF REACTIVE BLACK 5 DYE

100%

Filipkowska U., Jóźwiak T., Gache L., Bolozan L.

Progress on Chemistry and Application of Chitin and its Derivatives

2019

vol. 24

36 - 48

The influence of chitosan content in hydrogel beads on the sorption effectiveness of Reactive Black 5 (RB5) dye from aqueous solutions is presented in the following work. The dry mass of chitosan in the tested hydrogel chitosan sorbents was from 2 to 10%. The influence of pH (4–11) on the sorption effectiveness of RB5 on chitosan hydrogels as well as the sorption capacity of the tested chitosan sorbents in relation to RB5 were studied. The optimal pH of RB5 sorption was determined along with the pH at the potential at zero point charge (pHPZC) of the tested sorbents. The maximum sorption capacity of the tested sorbents, depending on the amount of chitosan dry mass in the hydrogel beads, was determined. The obtained data was fit to Langmuir 1, Langmuir 2, and Freundlich models.

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2 Progress on Chemistry and Application of Chitin and its Derivatives

2 2019

2 Bolozan L.

2 Filipkowska U.

2 Gache L.

2 Jóźwiak T.

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THE INFLUENCE OF SALINITY ON REACTIVE BLACK 5 DYE SORPTION EFFICIENCY ON HYDROGEL CHITOSAN SORBENTS

THE INFLUENCE OF CHITOSAN CONTENT IN HYDROGEL BEADS ON THE SORPTION EFFECTIVENESS OF REACTIVE BLACK 5 DYE