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Trace metals analysis of soil and edible plant leaves from abandoned municipal waste dumpsite in Owerri, Imo state, Nigeria

100%

Ibe F. C., Beniah O. I., Enyoh C. E.

World News of Natural Sciences

2017

vol. 13

27-42

Municipal refuse may increase heavy metal concentration in soil, even at low levels, and their resulting long-term cumulative health effects are among the leading health concerns all over the world. In this study, we investigated the concentration of heavy metals in soils and edible plant leaves grown in an abandoned dumpsite along Akachi road in Owerri municipality. The soil samples were collected at each plot using a soil auger at the depth of 0-10 cm. Leaves of dominant edible plant species were selected and collected from each sample plot. The samples were dried in an oven with forced air at 40 °C, milled to fine powder then digested with 10 ml concentrated HNO3 and 5 ml concentrated HClO4 and were analyzed for Cr, Cu, Fe, Mn, Al, and Zn, using an H183200 MultiParameter Bench Photometer. Result showed that metals in in the sampled soils included (in order of quantity) Cr: 150-280 >Fe: 116.50-203 >Cu: 12.4-18.8 >Mn: 0-20 >Al: 0.08-0.16 >Zn: 0-1.4 mg kg-1 Dw. Moreover, levels of metals in the edible plant leaves are in the order of: Zn>Fe>Cu>Al>Mn>Cr. Zn, in particular, was higher than FAO/WHO recommended limits. Still, application of Pollution Load Index and Ecological risk models showed that the area is unpolluted and safe for use. Daily Metal Intake estimates indicated that zinc is mostly consumed from the plant species. The trends in Transfer Factor for the heavy metal in vegetable samples studied were in order: Zn>Al>Cu>Mn>Fe>Cr. Therefore, abandoned solid waste dumpsites contained significant concentrations of heavy metals which are later absorbed and accumulated by plants growing it.

Comparative study of the properties of yellow and brown Cyperus esculentus L.

100%

Ihenetu S. C., Ibe F. C., Inyamah P. C.

World News of Natural Sciences

2021

vol. 35

25-37

The present research accounts for the physicochemical and phytochemical characteristics of yellow and brown Cyperus esculentus, which were subjected to standard chemical and biochemical analysis. The results obtained from the analysis of yellow tiger nut showed the following phytochemical properties: anthocyanin 0.82 ± 0.02 µg/ml, oxalate 1.43 ± 0.05 µg/ml, tannin 12.22 ± 0.10 µg/ml, rutin 39.19 ± 0.29 µg/ml, phenol 10.94 ± 0.05 µg/ml, lunamarine 38.99 ± 0.07 µg/ml, saponin 44.67 ± 0.15 µg/ml, ribalinidine 1.35 ± 0.03 µg/ml, phytate 0.33 ± 0.01 µg/ml, catechin 48.29 ± 0.04 µg/ml, and kaempferol 38.59 ± 0.02 µg/ml. The brown tiger nut showed the presence of the phytochemicals with values as: anthocyanin 0.01 ± 0.00 µg/ml, oxalate 2.66 ± 0.02 µg/ml, tannin 12.67 ± 0.04 µg/ml, rutin 43.99 ± 0.05 µg/ml, phenol 11.02 ± 0.10 µg/ml, lunamarine 39.66 ± 0.03 µg/ml, saponin 47.79 ± .06 µg/ml, ribalinidine 1.21 ± 0.04 µg/ml, phytate 0.28 ± 0.03 µg/ml, catechin 46.77 ± 0.05 µg/ml, and kaempferol 38.34 ± 0.15 µg/ml. The observed level of mineral elements in the tiger nut is in the increasing order of zinc > sodium > iron > copper > calcium > magnesium > potassium for yellow tiger nut, and for brown tiger nut the order is zinc > sodium > iron > copper > calcium > magnesium > potassium. The values of physical and chemical properties recorded for yellow tiger nut is in the increasing order of moisture > ash content > crude protein > crude fiber > crude fat > carbohydrate, the increasing order for brown tiger nut shows ash content > moisture > crude protein > crude fiber > crude fat > carbohydrate. This indicates that tiger nuts contain elevated carbohydrate levels, crude fat and protein. From the data obtained, the high potassium to low sodium ratio of the two species of tiger nuts consequently might be imperative in diet recommendations for patients with high blood pressure (high BP) and edema as well. The investigated tiger nut varieties are rich sources of the phytochemicals, oil and contain moderate amounts of protein. They are also rich sources of fiber and carbohydrates. The phytochemical constituents of the tiger nuts are important and could be of high commercial significance in both, research institutes and pharmaceuticals companies for manufacturing of new drugs and for therapeutic applications.

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2 World News of Natural Sciences

1 2021

1 2017

2 Ibe F. C.

1 Beniah O. I.

1 Enyoh C. E.

1 Ihenetu S. C.

1 Inyamah P. C.

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Trace metals analysis of soil and edible plant leaves from abandoned municipal waste dumpsite in Owerri, Imo state, Nigeria

Comparative study of the properties of yellow and brown Cyperus esculentus L.