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EN
The parametrized models are compared with counter-intuitive consequences of the non-relativistic Schrödinger treatment. For both 4f^{ q}, 5f^{ q} and d^{9} systems in condensed matter, the energy levels must be strongly influenced by correlation effects. The parametrization of intensities is conceptually very different for f^{ q} and d^{9} compounds. The bandwidths of absorption and luminescence are discussed and related to the Born-Oppenheimer factorization.
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vol. 125
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issue 3
778-781
EN
Silver nanoparticles with continuous size distribution from 10 to 20 nm were incorporated into porous glass produced using sol-gel technique. Positron annihilation lifetime spectroscopy was used to compare obtained material with an undoped reference glass. The positron annihilation lifetime spectroscopy measurement were made in a broad temperature range (from - 180C to 200°C). The experimental lifetime values were compared with the predictions of the extended Tao-Eldrup model of the temperature range. Experimental results for the reference material were in agreement with the model, except for a small discrepancy at low temperatures. In doped material substantial changes and non-monotonous temperature dependences of intensity and lifetime values were observed. Heating the material to 200C resulted in reorganization of the material structure.
EN
The purpose of this work was identification of luminescent lines occurring in natural carbonate-fluor-apatite (francolite) mineral. For identification of several rare earth ions occurring in natural francolite, the luminescence of rare earth ions was extensively studied in artificial mineral consisting of a pure francolite (not containing rare earth) of the composition Ca_{5}(PO_{4})_{3} (F,O):Ca_{5}(PO_{4})_{3} CO_{3} activated with Pr, Eu and Sm ions and then compared with the luminescence features observed in natural mineral.
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