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Magnetic properties of four nFeVO₄/(1-n)Co₃V₂O₈ samples obtained in reactions between FeVO₄ and Co₃V₂O₈ (n = 0.96, 0.86, 0.84 and 0.83, samples designated S1, S3, S4, S5, respectively) have been investigated by DC magnetisation in field cooling and zero-field-cooling modes and EPR. DC magnetic susceptibility showed paramagnetic behavior of all samples in high-temperature range (T > 20 K) and transition to antiferromagnetic state at 16-18 K (depending on sample iron content). Additional magnetic freezing at 8 K was registered for S3-S5 samples containing larger amount of cobalt. The Curie-Weiss law in 100-300 K temperature range indicates that Co²⁺ is in the high-spin state (S = 3/2). From the parameters of the hysteresis loop observed for the samples it was calculated that 0.58% of all magnetic (Fe³⁺, Co²⁺) ions were involved in the ferromagnetic states. EPR spectra of the samples were recorded in high temperature range (T > 90 K). The temperature dependence of the spectral parameters (resonance field, linewidth, integrated intensity) suggested the Fe³⁺ high-spin ions coupled by antiferromagnetic interaction and clusters of ions play major role in EPR spectra.
EN
The spin-1/2 Ising-Heisenberg trimerized chain in a magnetic field is revisited with the aim to explore the quantum entanglement and non-locality within the exactly solved spin system, which exhibits in a low-temperature magnetization curve two intermediate plateaux at zero and one-third of the saturation magnetization. The ground-state phase diagram involves two quantum (antiferromagnetic, ferrimagnetic I) and two classical (ferrimagnetic II, saturated paramagnetic) phases. We have rigorously calculated the concurrence and Bell function in order to quantify the quantum entanglement and non-locality at zero as well as non-zero temperatures. It is demonstrated that the entanglement can be thermally induced also above the classical ground states unlike the quantum non-locality, which means that the thermal entanglement is indispensable for a violation of the locality principle.
EN
A coupled spin-electron diamond chain with localized Ising spins placed on its nodal sites and mobile electrons delocalized over interstitial sites is explored in a magnetic field taking into account the difference between the Landé g-factors of the localized spins and mobile electrons. The ground-state phase diagram is constituted by two classical ferrimagnetic phases, the quantum unsaturated paramagnetic phase and the saturated paramagnetic phase. Both classical ferrimagnetic phases as well as the unsaturated paramagnetic phase are reflected in a low-temperature magnetization curve as intermediate magnetization plateaus. The unsaturated paramagnetic phase is quantum in its character as evidenced by the fermionic concurrence calculated for a pair of the mobile electrons hopping in between the interstitial sites. It is shown that the magnetic field can under certain conditions induce a quantum entanglement above the disentangled ground state.
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