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Electronic Constitution of Paramagnetic 3d Complexes and Positronium Conversion Rate Constants

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Fantola Lazzarini A., Lallarini E.
Acta Physica Polonica A
|
1993
|
vol. 83
|
issue 3
297-302
EN
The rate constants, k_{SE}, of ortho- into para-positronium spin conversion reactions promoted by paramagnetic 3d complexes may be correlated with their electronic constitution as it is described by the spin-orbit coupling and interelectronic repulsion parameters. The correlation is explained in terms of unpaired metal-electron delocalization towards the complex boundaries.
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