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EN
Energy level positions of the nickel 2+/1+ and cobalt 2+/3+ charge states have been used to estimate band edges for the valence and conduction bands of ZnSe-based alloys with cation (ZnCdSe) and anion (ZnSSe) substitution. Chemical trends in band offsets of heterostructures of Zn- or Mn-based II-VI compounds are analysed. Further on, the change of Ni^{2+}(3d^{8}) and Co^{2+}(3d^{7}) intra-d shell transition bands upon the alloying of host material is discussed.
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Excitonic Spectra of Cd_{1-x}Fe_{x}Te Crystals

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EN
Strong modification of the optical spectra near the band-gap edge is observed in Cd_{1-x}Fe_{x}Te crystals as compared to the spectra of a pure compound. The evolution of the luminescence spectra at the increase in Fe concentration is represented by the change of radiative recombination channels from dominantly (A^{0}, x) acceptor bound exciton emission in undoped CdTe to the free exciton luminescence in Cd_{1-x}Fe_{x}Te solid solutions.
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EN
Absorption and reflectivity measurements were carried out on Zn_{1-x}Mn_{x}Se:Ni solid solutions. The spectra demonstrate the radical change of the structure of internal Ni^{2+}(3d^{8}) transitions at the presence of the Mn ions and strong dependence on Mn concentration. The threshold energy ħω_{th} for the process of Ni photoionization to the valence band Ni^{2+}(3d^{8}) + ħω_{th} → Ni^{1+}(3d^{9}) + h is shifted to the lower energy by 30 meV, but hardly depends on x despite the essential increase in the energy gap.
EN
We studied the luminescence of bulk Zn_{1-x}Cd_{x}Se solid solutions, epitaxial ZnSe films and ZnSe_{1-x}S_{x}/ZnSe_{1-y}S_{y} superlattices at T=2-80 K. The analysis of the bands of exciton radiative annihilation with simultaneous emission of 1 or 2 LO phonons shows that the excitons in the studied samples can be considered as free particles with thermalized distribution of kinetic energies. In ZnSe_{1-x}S_{x}/ZnSe_{1-y}S_{y} superlattices a three-dimensional character of exciton motion was established. The periodic potential of superlattice perturbs the exciton wave vector and induces additional elastic scattering of excitons.
EN
Absorption and reflectivity measurements have been carried out for Zn_{1-x}Cd_{x}Se:Ni and ZnS_{x}Se_{1-x}:Ni solid solutions. Energy level positions of nickel 2+/1+ charge state have been used for estimation of band offsets for the valence and conduction bands of ZnCdSe/ZnSe and ZnSSe/ZnSe. Intra-shell transitions of Ni^{2+} were also studied.
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