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EN
The studies of time-resolved dose dependences of conductivity and luminescence in ZnSe crystals at various temperatures (8, 85, 295, and 430 K) under X-ray and UV-excitation have revealed that dose dependences under X-ray excitation build up much more slowly and are more informative in comparison with UV-excitation. It is due to high penetrating depth of X-ray radiation and respective involvement of a large sample volume in the kinetic processes. Also, due to the local inhomogeneity of the excitation in the absorption of X-quantum, a significant share of the generated electron-hole pairs recombine in this local area creating a scintillation pulse, and not participating in the conductivity. The delay in the onset of the X-ray conductivity buildup at 8 K for several seconds is due to the high efficiency of the localization of free carriers in the traps, all of which become deep at this temperature. The different buildups of various bands of luminescence of irradiation time can be explained by not only different concentration of luminescence centers but also by their localization in various sections of free charge carriers. Dose dependences of the luminescence and conductivity also show that the scintillation pulse amplitudes and the current pulse amplitudes of the X-ray conductivity are not constant during irradiation of the ZnSe crystals.
EN
Theoretical analysis of the ferro-elastic domain structure of a La_{0.95}Sr_{0.05}Ga_{0.9}Mg_{0.1}O_{2.925} crystal in three different crystallographic phases is presented. Parameters of these configurations are obtained using group theoretical approach, the method of spontaneous deformation as well as theoretical interpretation of twinning resulting from mechanical deformation (mechanical twinning theory). In the three phases of La_{0.95}Sr_{0.05}Ga_{0.9}Mg_{0.1}O_{2.95} - trigonal, orthorhombic and monoclinic - the parameters of ferro-elastic domain structures are determined; namely the quantity of orientation states, symmetry elements of connection between states, orientations and types of domain walls, tensors of spontaneous deformations of the perovskite-type cells for every orientation state, elements of twin shifts, which are needed for the reorientation of some orientation states to others. By using the found parameters of bidomain configurations a mechanism is proposed, which causes chevron-like domain configurations in compounds with martensitic phase transitions.
EN
An effect of lutetium co-doping on photoluminescent and thermoluminescent properties of the Mn²⁺-doped (Lu-Y)AP crystals (with Lu content from 0 to 20% with respect to Y) grown by the Czochralski technique has been studied. It was found that the maximum of the thermoluminescent peak at 200°C is shifted towards higher temperatures at Lu content more than 5%. At the same time the position of the second thermoluminescent peak near 350°C remains unchanged. The observed changes in the thermoluminescent peak position are discussed in terms of the point defects of the material.
EN
Spatial changes of optical properties of bulk LiNbO₃ crystal were investigated after annealing in CuO powder. The incorporation of copper ions into the crystal was confirmed by registration of additional absorption spectra that revealed formation of the absorption bands of both Cu⁺ (400 nm) and Cu²⁺ (1000 nm) ions. The changes of optical absorption caused by thermal treatment were registered along the direction of diffusion by the probe beam perpendicular to this direction. The anisotropy of diffusion was revealed. The maxima were observed on the depth dependences of additional absorption both for the wavelengths of 400 and 1000 nm for all main crystallographic directions. The concentrations of copper ions were calculated in accordance with the Smakula-Dexter formula. The X-ray diffraction study revealed reflexes which probably belong to CuNb₂O₆, CuNbO₃ and CuO. The halo was observed on these diffraction patterns that confirms the formation of the scattering centers (about 1 nm in diameter) in the near-surface region.
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