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2013 | 15 | 3 | 81-84

Article title

Removal of lindane from wastewater using liquid-liquid extraction process

Content

Title variants

Languages of publication

EN

Abstracts

EN
Pesticide pollution is a serious problem being faced. Harmful levels of pesticides are found in the water which is used for daily purposes. In the event of such a scenario, this paper presents a working solution for bringing down the Pesticide levels in the water to safe levels by using the method of liquid-liquid extraction. The experimental liquid-liquid equilibrium data on pesticide-water-solvent ternary mixtures at a temperature of 288.15 K are presented here. The pesticide used here is a chlorinated hydrocarbon called lindane found in the water (underground, land), beverages and foods. The solvents used are Petro-ether-Chloroform (1:1), Ethylene di chloride and n-hexane. The equilibrium generation diagram, triangular diagram, tie lines and bimodal curves as well as the distribution coefficient have been determined and reported. The petro-ether-chloroform was found to be the right solvent for the separation of lindane from wastewater because of high selectivity (25.36) and distribution coefficient (4). The extraction process is simulated into ‘C’ language

Publisher

Year

Volume

15

Issue

3

Pages

81-84

Physical description

Dates

published
1 - 09 - 2013
online
20 - 09 - 2013

Contributors

  • Affiliated to North Maharashtra University, Department of Biotechnology, Bambhori, Jalgaon, India-425 001
  • Govt. College of Engineering, Applied Science Dept., Jalgaon, India
  • Affiliated to University of Pune, Sir Visvesvaraya Institute of Technology, Nashik, India

References

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  • 2. Anon. (2003). All major cold drink brands in India have pesticide residues, Down Earth, vol. 12 no. 6, p. 31-35.
  • 3. WHO. (2004). Guidelines for drinking water quality. (http://www.who.int/water_sanitation_health/dwg/chemical/lindane.pdf)
  • 4. U.S. Environmental Protection Agency. (1994). Deposition of Air Pollutants to the Great Waters. First Report to Congress. EPA-453/R-93-055. Office of Air Quality Planning and Standards, Research Triangle Park, NC.
  • 5. Agency for Toxic Substances and Disease Registry (ATSDR). (1997). Toxicological Profile for Alpha-, Beta-, Gamma-, and Delta- Hexachlorocyclohexane (Update). Draft for Public Comment. U.S. Public Health Service, U.S. Department of Health and Human Services, Atlanta, GA.
  • 6. U.S. Department of Health and Human Services. (1993) Hazardous Substances Databank (HSDB, online database). National Toxicology Information Program, National Library of Medicine, Bethesda, MD .
  • 7. U.S. Environmental Protection Agency. (1999). Integrated Risk Information System (IRIS) on gamma-Hexachlorocyclohexane. National Center for Environmental Assessment, Office of Research and Development, Washington, DC.
  • 8. Gupta, V., Jain, C., Imran, A., Chandra, S. & Agarwal, S. (2002). Removal of lindane and mathion from wastewater using bagasse fly ash-a sugar industry waste, water research, vol. 36, (10), p. 2483-2490, PII: S0043-1354(01)00474-2.
  • 9. Jovan, L., Divna, K. & Magdalena, T. et al., (2006) Removal of atrazine ,lindane and diazinone from water by organo-zeolites, water research, vol. 40, p. 1079-1085, DOI: 10.1016/j.watres.2006.01.001.[Crossref]
  • 10. Hassan, A., Abed, M. & Ismael, A. (2009). Removal of lindane and melathion from wastewater by activated carbon prepeared from apricot stone, Ass. Univ. Bull. Environ. Res., vol. 12, (2), p. 1-8.
  • 11. Sumipa, D. & Chaudhari, S. (2012). Potentiality of sugarcane baggasse as an adsorbent for the removal of pesticides from drinking water, NeBIO, vol. 3, (2), p. 107-111.
  • 12. Kipopoulou, A., Zouboulis, A., Samara, C. & Kouimtzis, T. (2004). The fate of lindane in the conventional activated sludge treatment process, Chemosphere, vol. 55, p. 81-91, DOI: 10.1016/j.chemosphere.2003.11.020.[Crossref]
  • 13. Veena, S. & Singh, D. (2011). Biodegradation of lindane pesticide by non white-rots soil fungus Fusarium sp, World J. of Micro and Biotech, vol. 27, (8), p. 1747-1754.[WoS]
  • 14. Zheng, G., Selvam, A. & Wang, J. (2011). Rapid degradation of lindane (γ-hexachlorocyclohexane) at low temperature by sphingobium strains, Int. J. Biodet. & Biodegrd., vol. 65, (4), p. 612-618. DOI: 10.1016/j.ibiod.2011.03.005.[Crossref]
  • 15. Jaseetha, A. & Nilanjana, D. (2012). Remediation of lindane from environment - an overview, vol. 2, (1), p. 9-15.
  • 16. Robert, E.T. (1981). Mass Transfer Operations, 3rd edition, Mcgraw-Hill International series, p. 482-500.
  • 17. http://en.wikipedia.org/wiki/Hexane
  • 18. http://macro.lsu.edu/HowTo/solvents/dcm.htm
  • 19. http://ces.iisc.ernet.in/energy/HC270799/HDL/ENV/enven/vol346.htm
  • 20. http://www.microkat.gr/msds/lindane.htm

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_pjct-2013-0050
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