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2009 | 11 | 2 | 31-35

Article title

Acetylation of p-Aminophenol by Preyssler's anion [NaP5W30O110]14-, [NaP5 W29MoO110]14- with green condition at room temperature

Content

Title variants

Languages of publication

EN

Abstracts

EN
Synthesis of acetaminophen at green condition and room temperature in the presence of the Preyssler type heteropolyacids has been investigated in order to contribute toward clean technology, which is the most important need of the society. All of the catalysts are recyclable and reusable.

Publisher

Year

Volume

11

Issue

2

Pages

31-35

Physical description

Dates

published
1 - 1 - 2009
online
19 - 6 - 2009

Contributors

author
author
  • Cluster for Molecular Chemistry, Department of Organic Chemistry, Radboud University Nijmegen, The Netherlands
  • Department of Chemistry, Islamic Azad University, Mashhad, IRAN
author
  • Department of Chemistry, Islamic Azad University, Mashhad, IRAN
  • Department of Chemistry, Islamic Azad University, Mashhad, IRAN

References

  • Bamoharram, F. F., Heravi, M. M., Roshani, M., Jahangir, M. & Gharib, A. (2006). Preyssler catalyst, [NaP5W30O110]14-: A green, efficient and reusable catalyst for esterification of salicylic acid with aliphatic and benzylic alcohols. Applied Catalysis A: General. 302, 42-47.
  • Kozhevnikov, I. V. (2007). Sustainable heterogeneous acid catalysis by heteropoly acids. Journal of Molecular Catalysis A: Chemical. 262, 86-92.[WoS]
  • Kozhevnikov, I. V. (1998). Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions. Chem. Rev. 98, 171-198.
  • Kozhevnikov, I. V. Catalysts for fine chemical synthesis. Vol. 2. Catalysis by polyoxometalates. Wiley & Sons, Chichester, England, 2002, pp. 216.
  • Heravi, M. M., Derikvand, F. & Bamoharram, F. F. (2005). A catalytic method for synthesis of Biginelli-type 3,4-dihydropyrimidin-2 (1H)-one using 12-tungstophosphoric acid. J. Molecular Catalysis A: chemical. 242, 173-175.
  • Kozhevnikov, I. V. (2003). Friedel-Crafts acylation and related reactions catalysed by heteropoly acids. Applied Catalysis A: General. 256, 3-18.
  • Bamoharram, F. F., Heravi, M. M., Roshani, M., Jahangir, M. & Gharib, A. (2007). Effective direct esterification of butanol by eco-friendly Preyssler catalyst, [NaP5W30O110]14-. J. Mol. Catal. 271, 126-130.[WoS]
  • Heravi, M., Zadsirjan, V., Bakhtiari, K., Oskooie, H. A. & Bamoharram, F. F. (2007). Green and reusable heteropolyacid catalyzed oxidation of benzylic, allylic and aliphatic alcohols to carbonyl compounds. Catalysis Communications. 8, 315-318.
  • Kozhevnikov, I. V. (2002). Heteropoly acids and related compounds as catalysts for fine chemical synthesis. Wiley & Sons, Chichester, England, 2002, pp. 216.
  • Heravi, M. M., Ranjbar, L., Derikvand, F. & Bamoharram, F. F. (2006). H14[NaP5W30O110] as a heterogeneous recyclable catalyst for the synthesis of 1,5-benzodiazepines in refluxing ethanol. Journal of Molecular Catalysis A: Chemical. 261, 156-159.
  • Alizadeh, M. H., Razavi, H., Bamoharram, F. F. & Hassanzadeh, M. H. (2003). Novel Catalytic Acetylation of Alcohols with Preyssler's Anion, [NaP5W30O110]14-. Kinet. Catal. 44, 574-579.
  • Moffat, J. B. (2001). Metal-Oxygen Clusters: The Surface and Catalytic Properties of Heteropoly Oxometalates, Kluwer/Plenum Press: New York.
  • Okuhara, T., Misono, M. & Misono, M. (1996). Advances in Catalysis.Catalytic Chemistry of Heteropoly compounds. 41, 113-152.
  • Alizadeh, M. H., Harmalker, S. P., Jeannin, Y., Martin-Frere, J. & Pope, M. T. (1985). A Heteropolyanion with fivefold molecular symmetry that contains a nonlabile encapsulated sodium ion. The structure and chemistry of [NaP5W30O110]14-. J. Am. Chem. Soc. 107, 2662.
  • Kozhevnikov, I. V. (1987). Advances in catalysis by heteropoly acids. Advances in catalysis by heteropoly acids. Russ. Chem. Rev. 56(9), 811-825.[Crossref]
  • Bamoharram, F. F., Heravi, M. M., Roshani, M., Gharib, A. & Jahangir M. (2006). A catalytic method for synthesis of γ-butyrolactone, ϵ-caprolactone and 2-cumaranone in the presence of Preyssler's anion, [NaP5W30O110]14-, as a green and reusable catalyst. J. Mol. Catal. 252, 90-95.
  • Bassam El, A., Bregeault Jean-Marie, M. J. & Claudine, M. (1989). Oxidative cleavage of ketones by vanadium polyoxometalates and dioxygen. New J. Chem. 13, 173-175.
  • Hill, C. L. (1989) Catalytic Oxygenation of Unactivated C-H Bonds. Superior Oxo Transfer Catalysts and the Inorganic Porphyrin′. In Activation and Functionalization of Alkanes., ed., Wiley: New York, pp 243-279.
  • Romanelli, G., Autino, J. C., Baronetti, G. & Thomas, H. (2001). H. Efficient Deprotection of Phenol Methoxymethyl Ethers Using a Solid Acid Catalyst with Wells-Dawson Structure. Molecules. 6, 1006-1010.

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10026-009-0020-3
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