Research on the influence of parameters on hexafluoropropylene oxide oligomerization in the presence of complex amines

• Authors: Egbert Meissner , Agnieszka Wróblewska
• Languages of publication: EN

Abstracts

EN

Oligomers of hexafluoropropylene oxide were tested as potential materials for obtaining vari-ous compounds with unique properties, of which most important are chemical and thermal re-sistance. Two basic parameters influence the oligomerization process of hexafluoropropylene oxide: the type of the catalyst and the type of the solvent. Other parameters such as temperature and pressure have significantly less influence. The influence of tertiary amines as catalyst, the type of the solvent, temperature, pressure and catalyst concentration were tested in the process of hexafluoropropylene oxide oligomerization.

Keywords

EN

hexafluoropropylene oxide; oligomers of hexafluoropropylene oxide

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2007
• Volume: 9
• Issue: 3
• Pages: 98-100

Dates

published

1 - 1 - 2007

online

6 - 11 - 2007

Contributors

author

Egbert Meissner

• Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Agnieszka Wróblewska

• Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

References

• Millauer H., Schwertfleger W., Siegemund G,: Hexafluoropropylene oxide - a key compound in organofluorine chemistry, Angew. Chem. Int. Ed. Engl. 1985, 24, 161.[Crossref]
• Strutz H at al.: Method for the oligomerization of hexafluoropropene oxide, EP 0378797, 1990.
• Darling D.T. at al.: Polymerization of hexafluoropropylene oxide, EP 0154297, 1985.

Identifiers

DOI

10.2478/v10026-007-0064-1