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Number of results

Journal

2013 | 11 | 10 | 1634-1643

Article title

Use of direct immersion solid-phase microextraction on polyacrylate and polydimethylsiloxane stationary phases for simultaneous determination of the neutral and basic pharmaceuticals in wastewater

Content

Title variants

Languages of publication

EN

Abstracts

EN
Direct immersion solid-phase microextraction has been optimized and applied to the simultaneous determination of the neutral and basic pharmaceuticals: caffeine, carbamazepine, clomipramine, chlorprothixene and clotrimazole at low concentrations in municipal wastewater. Two absorption type stationary phases: polydimethylsiloxane (PDMS) and polyacrylate (PA) have been found to be most effective for extraction of target analytes. The separation and detection were carried out by gas chromatograph coupled with mass spectrometer working in the selected ion monitoring mode. The method was validated for linearity, detection and quantitation limits, selectivity and precision. The average correlation coefficient of the calibration curves was 0.9933. The LOD values in influent and effluent wastewater were in the range of 10–145 ng L−1 and 4–111 ng L−1, respectively, which were a bit higher than those in the deionized water due to matrix effect. The high values of distribution coefficient (K fs ) in PDMS/water and PA/water systems (log K fs between 3.05 and 4.23) indicates the very high applicability of these stationary phases for determination of carbamazepine, clomipramine, chlorprothixene and clotrimazole in water samples. [...]

Publisher

Journal

Year

Volume

11

Issue

10

Pages

1634-1643

Physical description

Dates

published
1 - 10 - 2013
online
19 - 7 - 2013

Contributors

  • Institute of Chemistry, University of Białystok, 15-399, Białystok, Poland
  • Institute of Chemistry, University of Białystok, 15-399, Białystok, Poland

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-013-0296-2
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