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Journal

2011 | 9 | 5 | 776-789

Article title

Analysis of crystallographic and structural data of polymeric FeM (M = transition metals, lanthanides) complexes

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EN

Abstracts

EN
This review covers crystallographic and structural data for almost fifty polymeric FeM complexes (M = transition Cu, Ag, Au, Mo, W, Mn, Co, Ni and Pt and lanthanide elements Sm, Er and Yb) where iron is involved in polymeric chains. The complexes are for the most part yellow or black, but there are complexes of brown, orange, red, purple, blue and green colour. The complexes crystallized in the monoclinic (by far prevails), triclinic, tetragonal, orthorhombic, trigonal, hexagonal and rhombohedral crystal classes. The iron atoms are found in oxidation states 0, +2 and +3, of which +3 by far prevails. The inner coordination spheres about the Fe(0) atom are tetrahedral (FeC4) or sandwiched (FeC10), Fe(II) atoms are six-coordinated, and Fe(III) are six or even seven-coordinated. The inner coordination about M atoms range from four- through six- to eight-coordinated. The shortest Fe-Fe, Fe-M (transition) and Fe-M (lanthanide) and M-M separations are: 8.08 Å, 3.033 Å for Fe-Cu, 3.010 Å for Fe-Yb and 2.505 Å for Mo-Mo.

Publisher

Journal

Year

Volume

9

Issue

5

Pages

776-789

Physical description

Dates

published
1 - 10 - 2011
online
24 - 7 - 2011

Contributors

author
  • Department of Inorganic Chemistry, Slovak Technical University, Radlinskeho 9, 812 37, Bratislava, Slovak Republic
author
  • Department of Inorganic Chemistry, Slovak Technical University, Radlinskeho 9, 812 37, Bratislava, Slovak Republic

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-011-0067-x
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