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Number of results

Journal

2009 | 7 | 3 | 542-549

Article title

Hydrolysis kinetics of p-nitrophenylpicolinate catalyzed by schiff base Mn(III) complexes in Gemini 16-2-16 micellar solutiony

Content

Title variants

Languages of publication

EN

Abstracts

EN
Two mono-Schiff base Mn(III) complexes (MnL2Cl, L=L1 and L2) were synthesized and employed as artificial hydrolases in catalyzing the hydrolysis of p-nitrophenylpicolinate (PNPP) in Gemini 16-2-16 micellar solution. The effect of different micelles and their complex structures on the catalytic hydrolysis of PNPP is discussed in detail. The observations showed that MnL 22Cl exhibited higher catalytic activity over MnL 12Cl under a comparable condition, which confirmed that an open active centre is essential for modulating the activities of the two enzyme mimics. Moreover, under the conditions employed, hydrolytic rates of PNPP induced by these Mn(III) complexes were faster in Gemini 16-2-16 micelles than that in the micellar solution of cetyltrimethylammonium bromide (CTAB), a conventional analogue of Gemini 16-2-16. [...]

Publisher

Journal

Year

Volume

7

Issue

3

Pages

542-549

Physical description

Dates

published
1 - 9 - 2009
online
21 - 6 - 2009

Contributors

author
  • Key Laboratory of Green Chemistry & Technology, School of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering, Sichuan Zigong, 643000, China
author
  • Key Laboratory of Green Chemistry & Technology, School of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering, Sichuan Zigong, 643000, China
author
  • Department of Chemistry and Environment Science, Chongqing University of Arts and Science, Chongqing Yongchuan, 402160, China
author
  • College of Chemistry and Chemical Engineering, West China Normal University, Sichuan Nanchong, 637002, China
author
  • Key Laboratory of Green Chemistry & Technology, School of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering, Sichuan Zigong, 643000, China

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-009-0043-x
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