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Number of results

Journal

2006 | 4 | 3 | 489-501

Article title

Surface properties of some carotenoids spread in monolayers at the air/water interface. Experimental and computational approach

Content

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Languages of publication

EN

Abstracts

EN
The surface pressure versus molecular area isotherms of some carotenoids: β,β-carotene-4-one (echinenone, ECH), β,β-carotene-4,4′-dione (canthaxanthin, CAN) and 4,4′-diapo-ω,ω-carotene-4,4′-dial (APO), spread at the air/water interface, are reported. A van der Waals type state equation is used to describe the high molecular area portions of the compression isotherms and interaction parameters within monolayers are derived. Quantum chemical semi-empirical SCF MO calculations (AM1 and PM3) are performed for the optimized geometries of molecules and dipole moments are calculated. Similar theoretical magnitudes are obtained by both methods. Surface properties, like collapse pressure, surface compressional modulus and interaction parameters are discussed in terms of dipole-dipole interactions, and correlations with the calculated quantities for the carotenoid molecules are analyzed. The orientation of the different carotenoid molecules in the monolayer is discussed.

Publisher

Journal

Year

Volume

4

Issue

3

Pages

489-501

Physical description

Dates

published
1 - 9 - 2006
online
1 - 9 - 2006

Contributors

author
  • Department of Physical Chemistry, “Babes-Bolyai” University of Cluj-Napoca, 400028, Cluj-Napoca, Romania
  • Department of Orthopaedic Surgery, “Iuliu Hatieganu” University of Medicine, 400015, Cluj-Napoca, Romania
author
  • Department of Physical Chemistry, “Babes-Bolyai” University of Cluj-Napoca, 400028, Cluj-Napoca, Romania
author
  • Department of Physical Chemistry, “Babes-Bolyai” University of Cluj-Napoca, 400028, Cluj-Napoca, Romania
  • Department of Physical Chemistry, “Babes-Bolyai” University of Cluj-Napoca, 400028, Cluj-Napoca, Romania
  • Department of Physical Chemistry, “Babes-Bolyai” University of Cluj-Napoca, 400028, Cluj-Napoca, Romania

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-006-0017-1
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