Synthesis and Luminescence Properties of Pr³⁺-Doped BiPO₄ Polycrystals

• Authors: V. Chornii , S. Nedilko , K. Bychkov , K. Terebilenko , M. Slobodyanik , V. Boyko
• Languages of publication: EN

Abstracts

EN

The results of synthesis, crystal structure characterization and luminescence properties study of the Pr³⁺-doped bismuth orthophosphate, BiPO₄, polycrystals are reported. It was found that doping of bismuth orthophosphate with praseodymium of concentration more than 1% leads to phase transition of BiPO₄ from so-called "high-temperature monoclinic" to "low-temperature monoclinic" structure. At room temperature studied samples revealed intensive red luminescence caused by radiation electronic transitions in the Pr³⁺ ions under their intrinsic f → f excitation at ³H₄→ ³P₁+¹I₆ absorption transition. Influence of phase transformation as well as multi-phonon and cross-relaxation processes on the luminescence of the Pr³⁺-doped BiPO₄ compounds were discussed.

Keywords

EN

78.55.Hx; 81.30.Hd

Discipline

• 78.55.Hx: Other solid inorganic materials
• 81.30.Hd: Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 4
• Pages: 843-846

Dates

published

2018-04

Contributors

author

V. Chornii

• Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine

author

S. Nedilko

• Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine

author

K. Bychkov

• Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine

author

K. Terebilenko

• Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine

author

M. Slobodyanik

• Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine

author

V. Boyko

• National University of Life and Environmental Sciences of Ukraine, 15 Geroiv Oborony Str., 03041 Kyiv, Ukraine

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Identifiers

DOI

10.12693/APhysPolA.131.843