Statistical Theory of Biaxial Nematic and Cholesteric Phases

• Authors: A. Kapanowski
• Languages of publication: EN

Abstracts

EN

A statistical theory of biaxial nematic and cholesteric phases is presented. It is derived in the thermodynamic limit at small density and small distortions. The considered phases are composed of short rigid biaxial or less symmetric molecules. The expressions for various macroscopic parameters involve the one-particle distribution function and the potential energy of two-body short-range interactions. The cholesteric phase is regarded as a distorted form of the nematic phase. Exemplary calculations are shown for several systems of molecules interacting via Corner-type potential based on the Lennard-Jones 12-6 functional dependence. The temperature dependence of the order parameters, the elastic constants, the phase twists, the dielectric susceptibilities, and the flexoelectric coefficients are obtained. The flow properties and defects in nematics are also discussed.

Keywords

EN

61.30.Cz; 77.84.Nh

Discipline

• 61.30.Cz: Molecular and microscopic models and theories of liquid crystal structure
• 77.84.Nh: Liquids, emulsions, and suspensions; liquid crystals(for structure of liquid crystals, see 61.30.-v)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2011
• Volume: 120
• Issue: 3
• Pages: 351-367

Dates

published

2011-09

received

2011-05-24

Contributors

author

A. Kapanowski

• Marian Smoluchowski Institute of Physics, Jagiellonian University, W.S. Reymonta 4, PL-30-059 Kraków, Poland

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Identifiers

DOI

10.12693/APhysPolA.120.351