Cobalt Additives Influence on Phase Composition and Defect Structure of Manganese Dioxide Prepared from Fluorine Containing Electrolytes

• Authors: G. Sokolsky , S. Ivanov , N. Ivanova , Ye. Boldurev , O. Kobulinskaya , M. Demchenko
• Languages of publication: EN

Abstracts

EN

Manganese dioxide samples were prepared from fluorine containing electrolytes with additives of Co^{2+} ions. Atomic absorption spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy with energy dispersive X-ray analysis were the methods of the samples characterisation. Manganese dioxide at the presence of cobalt forms nanosized ramsdellite structure crystallites of mostly needle-like morphology with significant content of hydroxide groups. The main phase state in manganese dioxide samples obtained at the presence of cobalt is γ-MnO_{2} with ramsdellite structure and low content of intergrowth defects. The sample doped both with lithium and cobalt can be indexed to a hollandite-type structure (tetragonal; space group I4/m) of α-MnO_{2}.

Keywords

EN

61.66.Fn; 61.72.-y; 85.40.Ry

Discipline

• 61.66.Fn: Inorganic compounds
• 85.40.Ry: Impurity doping, diffusion and ion implantation technology
• 61.72.-y: Defects and impurities in crystals; microstructure(for radiation induced defects, see 61.80.-x; for defects in surfaces, interfaces, and thin films, see 68.35.Dv and 68.55.Ln; see also 85.40.Ry Impurity doping, diffusion, and ion implantation technology; for effects of crystal defects and doping on superconducting transition temperature, see 74.62.Dh)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2010
• Volume: 117
• Issue: 1
• Pages: 86-90

Dates

published

2010-01

Contributors

author

G. Sokolsky

• National Aviation University, Cosmonaut Komarov Av. 1, 04058 Kiev 58, Ukraine

author

S. Ivanov

• National Aviation University, Cosmonaut Komarov Av. 1, 04058 Kiev 58, Ukraine

author

N. Ivanova

• Institute of General and Inorganic Chemistry of Ukrainian National Academy of Science, Palladin Av. 32-34, 252680 Kiev 142, Ukraine

author

Ye. Boldurev

• Institute of General and Inorganic Chemistry of Ukrainian National Academy of Science, Palladin Av. 32-34, 252680 Kiev 142, Ukraine

author

O. Kobulinskaya

• National Aviation University, Cosmonaut Komarov Av. 1, 04058 Kiev 58, Ukraine

author

M. Demchenko

• National Aviation University, Cosmonaut Komarov Av. 1, 04058 Kiev 58, Ukraine

References

• 1. M.S. Whittingham, Chem. Rev. 104, 4271 (2004)
• 2. P. Kofstad, Oxidat. Metals 44, 3 (1995)
• 3. A. Le, Gal La Salle, A. Verbaere, Y. Piffard, D. Guyomard, in: NATO Science Series, Vol. 85, Ed. C. Julien, Z.B. Stoinov, Kluwer Academic Publishers, Dordrecht 2000, p. 241
• 4. Y. Song, P.Y. Zavalij, M.S. Whittingham, J. Electrochem. Soc. 152, A762 (2005)
• 5. J.S. Rebello, P.V. Samant, J.L. Figueredo, J.B. Fernandes, J. Power Sources 153, 36 (2006)
• 6. S.L. Suib, Chem. Innovation 30, 27 (2000)
• 7. V.D. Makwana, L.J. Garces, J. Liu, J. Cai, Y.-C. Son, S.L. Suib, Catalysis Today 85, 225 (2003)
• 8. P.M. De Wolff, J.W. Visser, R. Giovanoli, R. Brutsch, Chimia 32, 257 (1978)
• 9. J. Brenet, J. Power Sources 4, 183 (1979)
• 10. P. Ruetschi, R. Giovanioli, J. Electrochem. Soc. 135, 2663 (1988)
• 11. H. Abbas, S.A. Nasser, J. Power Sources 58, 15 (1996)
• 12. P.M. de Wollf, Acta Crystallogr. 12, 341 (1959)
• 13. M. Kakazey, N. Ivanova, Y. Boldurev, S. Ivanova, G. Sokolsky, J.G. Gonzalez Rodriguez, M. Vlasova, J. Power Sources 114, 170 (2003)
• 14. Y. Chabre, J. Pannetier, Prog. Solid State Chem. 23, 1 (1995)
• 15. L.I. Hill, A. Verbaere, J. Solid State Chem. 177, 4706 (2004)
• 16. W. Bowden, T. Bofinger, F. Zhang, N. Iltchev, R. Sirotina, Y. Paik, H. Chen, C. Grey, S. Hackney, J. Power Sources 165, 609 (2007)
• 17. A.H. Heuer, A.Q. He, P.J. Hughes, F.H. Feddrix, ITE Lett. 1, B50 (2000)
• 18. C.-H. Kim, Z. Akase, L. Zhang, A.H. Heuer, A.E. Newman, P.J. Hughes, J. Solid State Chem. 179, 753 (2006)
• 19. D.G. Malpas, F.L. Tye, in: Handbook of Manganese Dioxides Battery Grade, Eds. D. Glover, B. Schumm Jr., A. Kozawa, IBA Inc & JEC Press Inc., Brunswick 1989, Ch. IV
• 20. N.D. Ivanova, S.V. Ivanov, Russian Chem. Rev. 62, 907 (1993)
• 21. N. Ivanova, Y. Boldurev, G. Sokolsky, I. Makeeva, Russ. J. Appl. Chem. 75, 1420 (2002)
• 22. G. Sokolsky, N. Ivanova, S. Ivanov, Ye. Boldyrev, in: 5th Spring Annual Meeting of the ISE, Doublin (Ireland), 2007, Book of Abstracts, p. 153
• 23. G. Sokolsky, N. Ivanova, Y. Boldurev, S. Ivanov, XVII Ukrainian Inorganic Chem. Conf. Proc., Lviv, 2008, p. 160
• 24. G. Sokolsky, N. Ivanova, S. Ivanov, T. Tomila, Ye. Boldyrev, Sci. Sintering 39, 273 (2007)
• 25. I.S. Makeeva, N.D. Ivanova, V.V. Trachevsky, Ukr. Khim. Zh. 66, 88 (2000)
• 26. A.B. Velichenko, R. Amadelli, G.L. Zucchini, D.V. Girenko, F.I. Danilov, Electrochim. Acta 45, 4341 (2000)
• 27. E. Machefaux, L.I. Hill, A. Verbaere, D. Guyomard, in: New Trends in Intercalation Compounds for Energy Storage and Conversion, Eds. K. Zaghib, C.M. Juilien, J. Prakash, Electrochemical Social Proceedings, Vol. PV 2003-20, Pennington 2003, p. 461
• 28. C. Pitteloud, M. Nagao, K. Itoh, R. Kanno, J. Solid State Chem. 181, 467 (2008)
• 29. K.M. Parida, S.B. Kanungo, Thermochim. Acta 66, 275 (1983)
• 30. N. Kijima, T. Ikeda, K. Oikawa, F. Izumi, Y. Yoshimura, J. Solid State Chem. 177, 1258 (2004)
• 31. N. Kumagai, T. Sasaki, S. Oshitari, S. Komaba, J. New Mater. Electrochem. Systems 9, 175 (2006)
• 32. G. Sokolsky, S. Ivanov, N. Ivanova, Y. Boldurev, Powder Metall. Met. Ceram. 45, 158 (2006)
• 33. C.S. Johnson, M.F. Mansuetto, M.M. Thackeray, Y. Shao-Horn, S.A. Hackney, J. Electrochem. Soc. 144, 2279 (1997)

Identifiers

DOI

10.12693/APhysPolA.117.86