Effect of Doping by Different Transition Metals on the Acoustical Properties of Alkali Borate Glasses

• Authors: M. Gaafar , F. El-Batal , M. El-Gazery , S. Mansour
• Languages of publication: EN

Abstracts

EN

Longitudinal and shear ultrasonic wave velocities were measured in binary Li_2O-2B_2O_3 glasses doped with different transition metal oxides (TMOs) (where TMO = V_2O_5, Fe_2O_3, Cr_2O_3, NiO, TiO_2, MnO_2 and CuO) using pulse echo technique. Measurements were carried out at 4 MHz frequency and at room temperature. Elastic moduli and some other physical parameters such as acoustic impedance, Debye temperature, thermal expansion coefficient, and latent heat of melting were calculated. Results indicated that these parameters depend upon the TMO modifier i.e., the ionic radius of the transition metal cation. Quantitative analysis has been carried out, in order to obtain more information about the structure of these glasses, based on bond compression model, and the Makishima and Mackenzie model, i.e., the cation-anion bond of each TMO.

Keywords

EN

61.43.Fs; 43.35.Ae; 62.20.Dc; 65.40.De

Discipline

• 65.40.De: Thermal expansion; thermomechanical effects
• 61.43.Fs: Glasses

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2009
• Volume: 115
• Issue: 3
• Pages: 671-678

Dates

published

2009-03

received

2008-02-26

(unknown)

2008-12-30

Contributors

author

M. Gaafar

• Ultrasonic Laboratory, National Institute for Standards, Tersa Str., P.O. Box 136, El-Haram, El-Giza 12211, Egypt

author

F. El-Batal

• Glass Research Department, National Research Center, El-Tahreer Str., Dokki, Cairo, Egypt

author

M. El-Gazery

• Ultrasonic Laboratory, National Institute for Standards, Tersa Str., P.O. Box 136, El-Haram, El-Giza 12211, Egypt

author

S. Mansour

• Department of Physics, Faculty of Science, Suez Canal University, Ismailia, Egypt

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Identifiers

DOI

10.12693/APhysPolA.115.671