Influence of Hydrostatic Pressure on the Zero-Field Splitting in NiSnCl_6·6H_2O

• Authors: A. Krupska , M. Krupski
• Languages of publication: EN

Abstracts

EN

The dependence of the crystal-field splitting parameter D in NiSnCl_6·6H_2O on hydrostatic pressure was determined by the electron paramagnetic resonance method, for the pressures up to 500 MPa. The derivative (∂D/∂p)_T as well as the temperatures and pressures at which the D-parameter reaches zero, were determined. The molecular mechanism responsible for the temperature and pressure changes of the D-parameter is similar to that one observed in the isomorphic NiSiF_6·6H_2O.

Keywords

EN

62.50.+p; 76.30.Fc

Discipline

• 76.30.Fc: Iron group (3d) ions and impurities (Ti-Cu)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2003
• Volume: 103
• Issue: 5
• Pages: 453-458

Dates

published

2003-05

received

2003-04-04

Contributors

author

A. Krupska

• Institute of Molecular Physics of the Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

M. Krupski

• Institute of Molecular Physics of the Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

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Identifiers

DOI

10.12693/APhysPolA.103.453