Local States of Tellurium in Isolated Helical Chains

• Authors: J. Stanek , P. Fornal , S. Hafner , A. Pfitzner
• Languages of publication: EN

Abstracts

EN

The local electronic state of Te in the helical chains of CuXY_{2(1-x)}Te_{2x} (X = Cl, Br; Y = Se, S) were studied using the Mössbauer spectroscopy of ^{125}Te at 10 K and 70 K. The isolated chains of Te in these compounds are less rigid than those in elemental Te. The determined data of quadrupole splittingΔ and Debye temperatureΘ_D are indicative of strong local ordering of Te in one of the two non-equivalent crystallographic positions. It was not possible to resolve crystallographic positions by the Mössbauer spectroscopy.

Keywords

EN

76.80.+y

Discipline

• 76.80.+y: Mössbauer effect; other γ-ray spectroscopy(see also 33.45.+x Mössbauer spectra—in atomic and molecular physics; for biophysical applications, see 87.64.kx; for chemical analysis applications, see 82.80.Ej)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2001
• Volume: 100
• Issue: 5
• Pages: 807-815

Dates

published

2001-11

received

2001-05-14

Contributors

author

J. Stanek

• Institute of Physics, Jagiellonian University of Cracow, Reymonta 4, 30-059 Cracow, Poland

author

P. Fornal

• Institute of Physics, Technical University of Cracow, 30-084 Cracow, Poland

author

S. Hafner

• Center of Materials Sciences, University of Marburg, 35032 Marburg, Germany

author

A. Pfitzner

• Department of Inorganic Chemistry, University of Siegen, Siegen, Germany

References

• 1. P. Vulliet, J.P. Sanchez, unpublished
• 2. C.E. Violet, R. Booth, Phys. Rev., 144, 225, 1986
• 3. A. Pfitzner, S. Zimmerer, Z. Anorg. Allg. Chem., 621, 969, 1995
• 4. A. Pfitzner, S. Zimmerer, Z. Anorg. Allg. Chem., 622, 853, 1995
• 5. F.J. Berry, in: Mossbauer Spectroscopy Applied to Inorganic Chemistry, Vol. 2, Ed. G.J. Lang, Plenum Press, New York 1987, p. 343
• 6. H. Binczycka, S.S. Hafner, J. Stanek, M. Tromel, Phys. Lett. A, 131, 135, 1988
• 7. P. Booland, B.L. Robinson, S. Jha, Phys. Rev. B, 2, 3463, 1970

Identifiers

DOI

10.12693/APhysPolA.100.807