Rationalization of Spectra of Rare Earths in Condensed Matter

• Authors: R. Reisfeld , C. Jørgensen
• Languages of publication: EN

Abstracts

EN

The parametrized models are compared with counter-intuitive consequences of the non-relativistic Schrödinger treatment. For both 4f^{ q}, 5f^{ q} and d^{9} systems in condensed matter, the energy levels must be strongly influenced by correlation effects. The parametrization of intensities is conceptually very different for f^{ q} and d^{9} compounds. The bandwidths of absorption and luminescence are discussed and related to the Born-Oppenheimer factorization.

Keywords

EN

71.70.Ch

Discipline

• 71.70.Ch: Crystal and ligand fields

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1993
• Volume: 84
• Issue: 5
• Pages: 1011-1019

Dates

published

1993-11

Contributors

author

R. Reisfeld

• Department of Inorganic Chemistry, Hebrew University, 91904 Jerusalem, Israe1

author

C. Jørgensen

• Section of Chemistry, University of Geneva, 30 Quai Ansermet, 1211 Geneva 4, Switzerland

Identifiers

DOI

10.12693/APhysPolA.84.1011