THE EFFECT OF A COMPOSITE CHITOSAN/COPPER(II) ION COATING ON THE CORROSION RESISTANCE OF GRADE 4 TITANIUM IN SALINE: PRELIMINARY RESULTS

• Authors: Bożena Łosiewicz , Patrycja Osak , Julian Kubisztal
• Languages of publication: EN

Abstracts

EN

In the present work, we successfully used electrophoretic deposition to produce a new composite chitosan-copper(II) [Cu(II]) ion coating on grade 4 titanium (Ti). We prepared the coating with an environmentally friendly in situ chemical reduction process from a 2% (v/v) aqueous acetic acid solution with 1 g dm–3 chitosan and 10 g dm–3 copper acetate at 20 V for 300 s at room temperature. We evaluated the relationship between physicochemical properties and corrosion resistance of the coatings with energy dispersive spectroscopy, Fourier-transform infrared spectroscopy, a scanning Kelvin probe, and electrochemical methods. The composite coating contained 2.1 ± 0.1 wt.% of Cu, which ensures antibacterial activity. We determined the mechanism and kinetics of the electrochemical corrosion of the composite chitosan–Cu(II) ion coating on grade 4 Ti in saline solution (0.9% sodium chloride) at 37°C. The surface modification makes grade 4 Ti a more attractive material for use in dentistry.

Keywords

EN

chitosan; composite; copper; corrosion; electrophoretic deposition; titanium

Discipline

• CHEMISTRY: CHEMISTRY

• Publisher: Polish Chitin Society
• Journal: Progress on Chemistry and Application of Chitin and its Derivatives
• Year: 2023
• Volume: 28
• Pages: 89-102

Contributors

author

Bożena Łosiewicz

• Institute of Materials Engineering, Faculty of Science and Technology, University of Silesia in Katowice, 75 Pułku Piechoty 1A Str., 41–500 Chorzów, Poland

author

Patrycja Osak

• Institute of Materials Engineering, Faculty of Science and Technology, University of Silesia in Katowice, 75 Pułku Piechoty 1A Str., 41–500 Chorzów, Poland

author

Julian Kubisztal

• Institute of Materials Engineering, Faculty of Science and Technology, University of Silesia in Katowice, 75 Pułku Piechoty 1A Str., 41–500 Chorzów, Poland

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• Document Type: article