DURABILITY OF CHITOSAN/CELLULOSE HYDROGEL BEADS REGENERATED FROM AN IONIC LIQUID IN ACIDIC AND BASIC MEDIA AND THEIR METAL ADSORPTIVE CHARACTERISTICS

• Authors: Michiaki Matsumoto , Sayumi Ishikawa , Tatsuya Kamigaki
• Languages of publication: EN

Abstracts

EN

Chitosan–cellulose gel beads were regenerated from an ionic liquid, and their application to a metal adsorbent was examined. The chitosan–cellulose gel beads, which were prepared from 1-ethyl-3-methyl imidazolium acetate, were more stable in the acidic and basic aqueous solutions than cellulose or chitosan. The adsorption of copper on chitosan–cellulose gel beads was examined, and the adsorption amount of copper ion increased with pH, suggesting that amino groups on chitosan were related to adsorption. The adsorption isotherm of copper, zinc, and nickel ions was well described by the Langmuir model, and the adsorption ability of these metal ions obeyed the Irving-Williams series. Fe3+, Mn2+, and Co2+ from a buffer solution and Pt4+, Au3+, and Pd2+ from a hydrochloric acid solution were not adsorbed on the chitosan–cellulose gel beads.

Keywords

EN

Chitin; Emim; adsorption; cellulose; copper; ionic liquid; nickel; zinc

Discipline

• CHEMISTRY: CHEMISTRY

• Publisher: Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
• Journal: Progress on Chemistry and Application of Chitin and its Derivatives
• Year: 2019
• Volume: 24
• Pages: 145 - 150

Contributors

author

Michiaki Matsumoto

• Department of Chemical Engineering and Materials Science, Doshisha University

author

Sayumi Ishikawa

• Department of Chemical Engineering and Materials Science, Doshisha University

author

Tatsuya Kamigaki

• Department of Chemical Engineering and Materials Science, Doshisha University

References

• [1] Varma, A. J., Deshpande, S. V., Kennedy, J. F.;(2004) Metal complexation by chitosan and its derivatives: a review. Carbohydrate Polymers 55, 77-93; DOI: 10.1016/j.carbopol. 2003.08.005
• [2] Li, N., Bai, R.; (2005) Copper adsorption on chitosan-cellulose hydrogel beads: behaviors and mechanisms. Separation and Purification Technology 42, 237-247; DOI: 10.1016/j.seppur.2004.08.002
• [3] Sun, X., Peng, B., Ji, Y., Chen, J., Li, D.; (2009) Chitosan (Chitin)/cellulose composite biosorbents prepared using ionic liquid for heavy metal ions adsorption. AIChE Journal 55, 2062-2069; DOI: 10.1002/aic.11797
• [4] Tran, C. J., Duri, S., Delneri, A., Franko, M.; (2013) Chitosan-cellulose composite materials: preparation, characterization and application for removal microcystin. Journal of Hazardous Materials 252-253. 355-366; DOI: 10.1016/j.hazmat.2013.02.046
• [5] Liu, Z., H. Wang, Liu, C., Jiang, Y., Yu, G., Mu, X, Wang, X.; (2012) Magnetic cellulose-chitosan hydrogels prepared from ionic liquids as reusable adsorbent for removal of heavy metals. Chemical Communications 48, 7350-7352; DOI: 10.1039/c2cc17795a
• [6] Peng, S., Meng, H., Ouyang, Y., Chang, J.; (2014) Nonporous magnetic cellulose-chitosan composite microspheres: preparation, characterization, and application for Cu(II) adsorption. Industrial and Engineering Chemistry Research 53, 2106-2113; DOI: 10.1021/ie402855t
• [7] Li, M., Wang Z., Li, B.; (2016) Adsorption behavior of congo red by cellulose/chitosan hydrogel beads regenerated from ionic liquid. Desalination and Water Treatment 57, 16970-16980; DOI: 10.1080/19443994.2015.1082945

• Document Type: article