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2014 | 19 | 65-71

Article title

MISCIBILITY AND INTERACTIONS IN CHITOSAN AND POLYACRYLAMIDE MIXTURES

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Abstracts

EN
In the present work, the results of Fourier transform infrared (FTIR) and atomic force microscopy (AFM) studies of films of chitosan acetate (ChA), polyacrylamide (PAM), and their mixtures are presented. The morphology of the ChA and PAM films and their mixtures was studied by tappingmode atomic force microscopy (AFM). The topography images were considered by determining the root mean square (RMS) deviation in the image data. The study of mixtures by AFM showed a completely different morphology when compared with pure components. The roughness of mixtures increases with the increase of ChA content but is significantly reduced after UV exposure. This may indicate a strong interaction between the polymeric components. The FTIR spectroscopy also supports the obtained results. The miscibility of polymer mixtures is related to interactions between the functional groups of the polymeric components.

Contributors

  • Faculty of Chemistry Nicolaus Copernicus University

References

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  • 5. Lewandowska K., (2012) Progress on Chemistry and Application of Chitin and Its Derivatives, Monograph, Vol. XVII, Polish Chitin Society, In: Jaworska M. (ed), Lodz, pp. 53-58.
  • 6. Li R, Xiong Ch, Dong L; (2011) Preparation of the high dielectric performance flexible materials achieved by polyacrylamide/poly(vinylidene fluoride) blends. e-Polymers 11, 892-897, DOI: 10.1515/ epoly.2011.11.1.892.
  • 7. Zhang Z, Peng J, Huang L, Zhai M, Li J, Wei G; (2006) Studies on radiation degradation of chitosan in aqueous solutions. Acta Polym Sin 7, 841-847.
  • 8. Sionkowska A, Skopinska-Wisniewska J, Planecka A, Kozlowska J; (2010) The influence of UV irradiation on the properties of chitosan films containing keratin. Polym Deg Stab 95, 2486-2491, DOI: 10.1016/j.polymdegradstab.2010.08.002.

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article

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bwmeta1.element.psjd-cabc42af-2b2e-427b-954f-2f5e5fa5cc63
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