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2016 | 21 | 135-146
Article title

CYCLICAL METAL ADSORPTION AND DESORPTION THROUGH SLUDGE IMMOBILIZED IN CHITOSAN MEDIA

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Abstracts
EN
In this research, a cyclical adsorption/desorption of cadmium and zinc from solutions containing a single metal or its mixture in ratio of 1:1 and 1:2 using immobilized activated sludge in the chitosan (ASC) was examined. In the adsorption studies, the optimal dose of ASC was 4 g/L. The highest desorption efficiency was achieved for 1M HNO3. Both adsorption and desorption occurred in accordance with a pseudo-second order reactions which is confirmed by R2 values. Mass of zinc adsorbed and desorbed in one cycle from a solution containing a single metal was 0.78 and 0.40 mmol/g d.w. when cadmium was lower (respectively 0.41 and 0.21 mmol/g d.w.). In subsequent cycles, both metals were adsorbed and desorbed at a lower efficiency. The highest efficiency of desorption was observed for a mixture of Cd:Zn in the ratio of 1:1 and 1:2, respectively 86% and 89% of cycle1, whereas for the zinc it was 70% and 53%. Desorption efficiency of both metals and its mixtures, in subsequent cycles gradually decreased.
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Year
Volume
21
Pages
135-146
Physical description
Contributors
  • Department of Biotechnology in Environmental Protection, University of Warmia and Mazury in Olsztyn ul. Słoneczna 45g,10–702 Olsztyn, Poland, mkuczajowska@uwm.edu.pl
  • Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul. Warszawska 117, 10–720 Olsztyn, Poland
  • Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul. Warszawska 117, 10–720 Olsztyn, Poland
  • Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul. Warszawska 117, 10–720 Olsztyn, Poland
References
  • [1] Vijayaraghavan K, Yun Y; (2008) Bacterial biosorbents and biosorption. Biotechnol Adv 26, 266–291. DOI: 10.1016/j.biotechadv.2008.02.002
  • [2] Park D, Yun YS, Park JM; (2010) The past, present, and future trends of biosorption. Biotechnol Bioproc E 15, 86–102. DOI: 10.1007/s12257-009-0199-4
  • [3] Plaza Cazón J, Viera M, Donati E, Guibal E; (2013) Zinc and cadmium removal by biosorption on Undaria pinnatifida in batch and continuous processes. J Environ Manage 129, 423–434. DOI:10.1016/j.jenvman.2013.07.011
  • [4] Abdel –Aty AM, Nabila S, Ammar NS, Ghafar HHA, Ali RK; (2013) Biosorption of cadmium and lead from aqueous solution by fresh water alga Anabaena sphaerica biomass. J Adv Res 4, 367–374. DOI: 10.1016/j.jare.2012.07.004
  • [5] El-Shafey EI; (2010) Removal of Zn(II) and Hg(II) from aqueous solution on a carbonaceous sorbent chemically prepared from rice husk. J Hazard Mat 175, 319 – 327. DOI: 10.1016/j.hazmat.2009.10.006
  • [6] Palma G, Freer J, Baeza J; (2003) Removal of metal ions by modified Pinus radiate bark and tannins from water solution. Wat Res 37, 4974–4980. DOI: 10.1016/j.watres.2003.08.008
  • [7] Šćiban M, Radetić B, Kevrešan Ž, Klašnja M; (2007) Adsorption of heavy metals from electroplating wastewater by wood sawdust. Bioresour Technol 98, 402 – 409. DOI: 10.1016/j.biortech.2005.12.014
  • [8] Xiong C; (2010) Adsorption of cadmium(II) by chitin. J Chem Soc Pak 32, 429–435.
  • [9] Shaheen SM, Eissa FI, Ghanem KM, Gamal El-Din HM, Al Anany FS; (2013) Heavy metals removal from aqueous solutions and wastewaters by using various byproducts. J Environ Manage 128, 514–521. DOI: 10.1016/j.jenvman.2013.05.061.
  • [10] Sargın I, Kaya M, Arslan G, Baran T, Ceter T; (2015) Preparation and characterisation of biodegradable pollen–chitosan microcapsules and its application in heavy metal removal. Biores Technol 177,1–7. DOI: 10.1016/j.biortech.2014.11.067.
  • [11] Khosravan A, Lashkari B; (2011) Adsorption of Cd(II) by Dried Activated Sludge. Iranian J Chem Eng 8(2), 41–56.
  • [12] Kumar PS, Gayathri R; (2009) Adsorption of Pb2+ ions from aqueous solutions onto bael tree leaf powder: isotherms kinetics and thermodynamics study. Journal of Eng. Sci Technol 4(4), 381 – 399.
  • [13] Ong S, Toorisaka E, Hirata M, Hano T; (2010) Adsorption and toxicity of heavy metals on activated sludge. ScienceAsia 36, 204– 209.
  • [14] Gadd GM; (2009) Biosorption: critical review of scientific rationale, environmental importance and significance for pollution treatment. J Chem Technol Biotechnol 84, 13–28. DOI: 10.1002/jctb.1999
  • [15] Mack C, Wilhelmi B, Duncan JR, Burgess JE; (2007) Biosorption of precious metals. Biotechnol Adv 25, 264–271. DOI: 10.1016/j.biotechadv.2007.01.003
  • [16] Dhankhar R, Hooda A; (2011) Fungal biosorption – an alternative to meet the challenges of heavy metal pollution in aqueous solutions. Environ Technol 32, 467–491. DOI:10.1080/09593330.2011.572922
  • [17] Liu Y, Liao T, He Z, Li T, Wang H, Hu X, Guo Y, He Y; (2013) Biosorption of copper(II) from aqueous solution by Bacillus subtilis cells immobilized into chitosan beads. Trans Nonferrous Met Soc China 23, 1804−1814. DOI:10.1016/S1003-6326(13)62664-3
  • [18] Wan M, Wang C, Chen C; (2013) The Adsorption Study of Copper Removal by Chitosan-Coated Sludge Derived from Water Treatment Plant. Int J Enviro Sci Dev 4(5)
  • [19] Rangel-Mendeza JR, Monroy-Zepedab R, Leyva-Ramosb E, Diaz-Floresa PE, Shirai K; (2009) Chitosan selectivity for removing cadmium (II), copper (II), and lead (II) from aqueous phase: pH and organic matter effect. J Hazard Mater 162, 503–511. DOI: 10.1016/j.jhazmat.2008.05.073
  • [20] Kuczajowska-Zadrożna M, Filipkowska U, Jóźwiak T, Szymczyk P; (2015) Biosorption/desorption of cadmium(II)and zinc (II) from aqueous solutions by activated sludge immobilized onto chitosan beads. P C A C D XX, 142–155. DOI: 10.15259/PCACD.20.13
  • [21] Stanley WI, Watters GG, Chan B; (1975) Lactase and other enzymes Bound to chitin with glutaraldehyde. Biotechnol Bioeng XVII, 315–325. DOI: 10.1002/bit.260170303
  • [22] Esposito A, Paganelli F, Lodi A, Solisio C, Veglio F; (2001) Biosorption of heavy metals by Sphaerotilus natans: an equilibrium study at different pH and biomass concentrations. Hydrometallurgy 60, 129–41. DOI:10.1016/S0304-386X(00)00195-X
  • [23] Fomina M, Gadd GM; (2014) Biosorption: current perspectives on concept, definition and application. Bioresour Technol 160, 3–14. DOI: 10.1016/j.biortech.2013.12.102
  • [24] Kuczajowska-Zadrożna M, Filipkowska U; (2015) Kinetics of desorption of heavy metals and their mixtures from immobilized activated sludge. Desalin Water Treat DOI:10.1080/19443994.2015.1031708
  • [25] Njikam E, Schiewer S; (2012) Optimization and kinetic modeling of cadmium desorption from citrus peels: A process for biosorbent regeneration. J Hazard Mat 213– 214, 242– 248. DOI: 10.1016/j.jhazmat.2012.01.084
  • [26] Deng PY, Liu W, Zeng BQ, Qiu YK, Li LS; (2013) Sorption of heavy metals from aqueous solution by dehydrated powders of aquatic plants. Int J Environ Sci Technol 10, 559–566. DOI: 10.1007/s13762-013-0186-3
  • [27] Chen YW, Wang JL; (2012). The characteristics and mechanism of Co(II) removal from aqueous solution by a novel xanthate-modified magnetic chitosan. Nucl Eng Des 242, 452–457. DOI:10.1016/j.nucengdes.2011.11.004
  • [28] Wu SJ, Liou TH, Yeh CH, Mi FL, Lin TK; (2013) Preparation and characterization of porous chitosan-tripolyphosphate beads for copper(II) ion adsorption. J Appl Polym Sci 127, 4573–4580. DOI: 10.1002/app.38073
  • [29] Reyhanitabar N, Karimian; (2008) Kinetics of copper desorption of selected calcareous soils from Iran, American-Eurasian J Agric Environ Sci 4 (3), 287–293.
  • [30] Jho EH, Lee SB, Kim YJ, Nam K; (2011) Facilitated desorption and stabilization of sediment-bound Pb and Cd in the presence of birnessite and apatie. J Hazard Mat 188, 206–211.
Document Type
article
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Identifiers
YADDA identifier
bwmeta1.element.psjd-c607d270-f22e-451e-882f-99d97b6b9c05
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