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2019 | 24 | 106 - 118
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The Langmuir-Blodgett technique was used to transfer the monolayers of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) from the subphase containing chitosan (Ch) and/or titanium(IV) oxide (TiO2) and/or hyaluronic acid (HA) on glass plates after a low-temperature air plasma treatment. The surface free energy and its components were determined on the basis of advancing and receding contact angle measurements of water (W), formamide (F), and diiodomethane (DM). To estimate the total surface free energy (𝛾𝑠𝑡𝑜𝑡), the contact angle hysteresis (CAH) model was used, and the obtained data were compared with the results calculated from the Lifshitz-van der Waals/acid–base (LWAB) approach. It was found that the subphase components modify the surface of the phospholipid monolayer by changing the type and magnitude of interactions. They were reflected as significant differences in the obtained values of total surface free energy and its components. These findings can help in the development of composite materials, thereby expanding the spectrum of applications for chitosan, TiO2, and HA, as well as understanding the interactions between biomaterial and cell.
106 - 118
Physical description
  • Department of Interfacial Phenomena, Faculty of Chemistry, Maria Curie-Skłodowska University
  • Department of Interfacial Phenomena, Faculty of Chemistry, Maria Curie-Skłodowska University
  • Department of Interfacial Phenomena, Faculty of Chemistry, Maria Curie-Skłodowska University
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