Synthesis and spectral correlation studies of some substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazines

• Authors: R. Arulkumaran , V. Manikandan , P. Christuraj , G. Thirunarayanan
• Languages of publication: EN

Abstracts

EN

About ten substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazine compounds have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. From infrared spectra, the CN and N+N vibrational frequencies (cm-1) of the hydrazines have been assigned. From NMR spectra, the chemical shifts (, ppm) of CH proton and C(C6H5)2 carbons of the hydrazines have been assigned. These data are correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral data have been discussed.

Keywords

EN

(E)-1-Benzylidene-2-(diphenylmethylene) hydrazine; IR and NMR spectra; Hammett Correlations

Discipline

• CHEMISTRY: CHEMISTRY

• Publisher: Scientific Publishing House „DARWIN”
• Journal: World Scientific News
• Year: 2017
• Volume: 62
• Pages: 93-110

Contributors

author

R. Arulkumaran

• PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram - 608102, India

author

V. Manikandan

• PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram - 608102, India

author

P. Christuraj

• PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram - 608102, India

author

G. Thirunarayanan

• Department of Chemistry, Annamalai University, Annamalainagar - 608002, India,

References

• [1] T. W. Bell and A. T. Papoulis, Angew. Chem. Int. Ed. Engl., 31 (1992) 749-751.
• [2] A. I. Khodair and P. Bertrand, Tetrahedron., 54 (1998) 4859-4872.
• [3] E. E. Schweizer, Z. Cao, A. L. Rheigold and M.Bruch, J. Org. Chem., 58 (1993) 4339-4345.
• [4] A. Hashidzume, A. Tsuchiya, Y. Morishima and M. Kamatchi, Macromolecules, 33(7) (2000) 2397-2402.
• [5] R. Centore and C. Garzhillo, J. Chem. Soc., Perken Trans., 2(1) (1997) 79-84.
• [6] S. Radl, Aldrichimica Acta., 30(3) (1997) 97-100.
• [7] G. Y. Lee, Y. Her and J. G. June, Bull. Kor. Chem. Soc., 20 (1999) 1359-1367.
• [8] K. J. Lee, Y. Her and J. G. June, Bull. Kor. Chem. Soc., 20 (1999) 332-341.
• [9] H. Suschitzky and R. E. Walrond, J. Chem. Soc., Perken Trans., 1 (1977) 47-52.
• [10] Y. W. Ho, J. Chin. Chem. Soc., 54(4) (2007) 1075-1085.
• [11] R. M. Mohareb, J. Z. Ho and F. O. Alfarouk, J. Chin. Chem. Soc., 54(4) (2007) 1053-1066.
• [12] T. I. El-Emary, J. Chin. Chem. Soc., 54(4) (2007) 507-518.
• [13] K. M. Dawood, A. M. Farag and H. A. Abdel Aziz, J. Chin. Chem. Soc., 53 (2006) 873-880.
• [14] A. R. Farghaly and A. H. J. Chin. Chem. Soc., 51 (2004) 147-151.
• [15] A. Bodtke, W. D. Pfeiffer, N. A. Hrens and P. Langer, Tetrahedran, 61 (2005) 10926-10929.
• [16] A. I. Vogel, Text Book of practical organic chemistry, 4th ed, ELBS and Longman, Londan, 1978.
• [17] P. A. S. Smith, Derivatives of hydrazones and other Hydronitrogens having N-N bonds, Benjamin, Londan and references cited there in pp (1983) 43-49.
• [18] H. M. Nanjundaswany and M. A. Pasha, Synth. Commun, 36 (2006) 31-61.
• [19] S. N. Shah and N. K. Chudger, Molecules, 5 (2000) 657-664.
• [20] G. S. Singh and K. Kopo, Ind. J. Chem, 41(B) (2002) 17-36.
• [21] H. Logmani-Khouzami, M. M. Sadeghi, J. Safari and M. S. M. J. Abdorrezaie, Jafapishen, Chem, Res, Synop, (2001) 80-81.
• [22] C. Effling, Am. Chem, pharama, 35 (1840) 241-246.
• [23] H. Schiff, Am, Sppl, 3 (1864) 343-350.
• [24] B. De. Clercq and F. Verpoof, J. Mol. Catal, A. Chem, 180(1) (2002) 67-76.
• [25] M. M. El-ajaily, M. M. Abou-Krsha, A. M. Etorki, F. S. Alassbaly and A. A. Maihub, J. Chem. Pharm, Res., 5(12) (2013) 933-938.
• [26] K. S. Kumar, S. Ganguly, R. Veerasamy and E. D. Clercq, Eur. J. Med. Chem., 45 (2010) 5474-5479.
• [27] A. L. Nivorozhkin, H. Tofflund, P. L. Jorgensen and L. E. Nivorozhkin, J. Chem. Soc., Dalton. Tran, (1996) 1215-1221.
• [28] A. K. Maldhure and A. S. Aswar, J. Ind. Chem. Soc., 86 (2009) 697-782.
• [29] A. K. Maldhure, A. S. Aswar, Wor. J. Chem. Soc., 4(2) (2009) 207-209.
• [30] S. K. Megalla, G. S. Sterens, C. A. Mcgveen, A. Y. Chen and C. Yu, J. med. Chem., 37(20) (1994) 3434-3439.
• [31] A.Y. Vibhure, S. S. Mokle, Y. S. Maluor, Y. B. Vibhur vasant and M. Gurav., Bull. Cata. Soc. Ind., 8 (2009) 164-168.
• [32] A. Mendoza, R. Meléndrez-Luevano, M. Blanca, C. Vivas, C. D. Lozano-Márquez and V. Carranza, Acta. Cryst. Sec. Struct., 68(2) (2012) 0434.
• [33] G. Shanker, M. Prehm, C. V. Yelamaggad and C. Tschierske, J. Mat. Chem., 21 (2011) 5307-5311.
• [34] B. Krishnakumar, M. Swaminathan, Catal. Commun., 16 (2011) 50-55
• [35] S. P. Sakthinathan, R. Suresh, V. Mala, K. Sathiyamoorthi, D. Kamalakkannan, K. Ranganathan, R. Arulkumaran, S. Vijayakumar, R. Sundararajan, G. Vanangamudi and G. Thirunarayanan, Int. Lett. Chem. Phy. Astro., 6 (2013) 77-90.
• [36] R. Arulkumaran, S. Vijayakumar, S.P. Sakthinathan, D. Kamalakkannan, K. Ranganathan, R. Suresh, R. Sundararajan, G. Vanangamudi and G. Thirunarayanan, J. Chil. Chem. Soc. 58(2) (2013) 1670-1684.
• [37] S. P. Sakthinathan, R. Suresh, V. Mala, K. Sathiyamoorthi, D. Kamalakkannan, K. Ranganathan, S. John Joseph, Int. J. Sci. Res. Know. 1(11) (2013) 472-483.
• [38] C. G. Swain and E. C. Lupton, J. Am. Chem. Soc. 90 (1968) 4328-4337.

• Document Type: article