Synthesis and spectral correlation studies of some substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazines

• Authors: R. Arulkumaran , V. Manikandan , P. Christuraj , G. Thirunarayanan
• Languages of publication: EN

Abstracts

EN

About ten substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazine compounds have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. From infrared spectra, the CN and N+N vibrational frequencies (cm-1) of the hydrazines have been assigned. From NMR spectra, the chemical shifts (, ppm) of CH proton and C(C6H5)2 carbons of the hydrazines have been assigned. These data are correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral data have been discussed.

Keywords

EN

(E)-1-Benzylidene-2-(diphenylmethylene) hydrazine; Hammett Correlations; IR and NMR spectra

Discipline

• CHEMISTRY: CHEMISTRY

• Publisher: Scientific Publishing House „DARWIN”
• Journal: World Scientific News
• Year: 2017
• Volume: 62
• Pages: 93-110

Contributors

author

R. Arulkumaran

• PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram - 608102, India

author

V. Manikandan

• PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram - 608102, India

author

P. Christuraj

• PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram - 608102, India

author

G. Thirunarayanan

• Department of Chemistry, Annamalai University, Annamalainagar - 608002, India

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• Document Type: article