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2014 | 19 | 73-78

Article title

VISCOMETRIC STUDIES OF CHITOSAN/POLYACRYLAMIDE MIXTURES

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Abstracts

EN
Polymer-polymer interactions and miscibility for chitosan (Ch) and partially hydrolysed polyacrylamide (HPAM) have been investigated using dilute solution viscosity. The intrinsic viscosity, [η], and the viscosity interaction parameters, bm, have been determined for the binary (solvent/polymer) and ternary (solvent/polymer A/polymer B) systems. Degree of miscibility of these polymer mixtures was estimated on the basis of two criteria. The final result depends on (i) the applied extrapolation method used for determination of the interaction parameters, (ii) the assumed miscibility criteria, and (iii) the blend composition.

Contributors

  • Faculty of Chemistry Nicolaus Copernicus University
  • Faculty of Chemistry Nicolaus Copernicus University
  • Faculty of Chemistry Nicolaus Copernicus University

References

  • 1. Roberts, GAF; (1992) Chitin chemistry; 1st ed., Macmillan Press Ltd.; London.
  • 2. Sionkowska A; (2011) Current research on the blends of natural and synthetic polymers: review. Prog Polym Sci 36, 1254-1276, DOI: 10.1016/j.progpolymsci.2011.05.003.
  • 3. Lewandowska K; (2007) Comparative studies of rheological properties of polyacrylamide and partially hydrolysed polyacrylamide solutions. J App Polym Sci 103, 2235-2241, DOI: 10.1002/app.25247.
  • 4. Krigbaum WR, Wall FT; (1950) Viscosities of binary polymeric mixtures. J Polym Sci 5, 505-514.
  • 5. Garcia R, Melad O, Gómez, CM, Figueruelo JE, Campos A; (1999) Viscometric study on the compatibility of polymer-polymer mixtures in solution. Eur Polym J 35, 47-55, DOI: 10.1016/S0014-3057(98)00106- 2.
  • 6. Catsiff EH, Hewett WA; (1962) The interaction of two dissimilar polymers in solution. J Appl Polym Sci 6, S30-S32, DOI: 10.1002/app.1962.070062322.
  • 7. Chee KK; (1990) Determination of polymer-polymer miscibility by viscometry. Eur Polym J 26, 423- 426, DOI: 10.1016/0014-3057(90)90044-5.
  • 8. Lewandowska K; (2005) The miscibility of poly(vinyl alcohol)/poly(N−vinylpyrrolidone) blends investigated in dilute solutions and solids. Eur Polym J 41, 55-64, DOI: 10.1016/j.eurpolymj.2004.08.016.
  • 9. Lewandowska K; (2011) Viscometric studies of microcrystalline chitosan/poly(vinyl alcohol) mixtures. Progress on Chemistry and Application of Chitin and Its Derivatives, volume XVI, Polish Chitin Society, Lodz, 43-47.
  • 10. Lewandowska K; (2013) Viscometric studies in dilute solution mixtures of chitosan and microcrystalline chitosan with poly(vinyl alcohol). J Solution Chem 42, 1654-1662, DOI: 10.1007/s10953-013-0053-3.
  • 11. Huggins MH; (1942) The viscosity of dilute solutions of long-chain molecules. IV. Dependence on concentration. J Am Chem Soc 64, 2716-2718, DOI: 10.1021/ja01263a056.
  • 12. Bohdanecký M, Kovář I; (1982) Viscosity of Polymer Solution. Vol. 2 In: Jenkins AD (ed.) Elsevier Science, Amsterdam.
  • 13. Dondos A, Christopoulou V, Papanagopoulos D; (1999) The influence of the molecular mass of two incompatible polymers on their miscibility in the solid state without compatibiliser after casting from solution. J Polym Sci Part: B Polym Phys 37, 379-387, DOI: 10.1002/(SICI)1099- 0488(19990215)37:4<379::AID-POLB11>3.0.CO;2-K.

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bwmeta1.element.psjd-abcfb6c4-5d5e-490e-beda-90074c5ab594
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