USE OF CHITOSAN ADSORBENTS FOR DYE REMOVAL IN THE AIR-LIFT REACTOR

• Authors: Urszula Filipkowska , Tomasz Jóźwiak , Magdalena Filipkowska
• Languages of publication: EN

Abstracts

EN

Adsorption tests in the air-lift reactor were carried out for six dyes – four anionic (RR11, RB5, RB8, and RR18) and two cationic (BV10 and BG 4) – as well as three adsorbents – chitosan flakes, chitosan in the form of beads, and modified sawdust immobilised in chitosan (adsorbent 3). The dye concentration in the inflow to the reactor in all the conducted test series was 10 mg/dm3; the amount of adsorbent was also constant at 10 g dry matter (d.m./dm3, and the flow rate was 0.1 V/h. For all tested dyes, the obtained maximum adsorption capacity was high and ranged from 3802 to 2203 mg/g d.m. for chitosan flakes, from 3312 to 2076 mg/g d.m. for chitosan beads, and from 2734 to 2148 mg/g d.m. for modified sawdust immobilised in chitosan. The immobilisation of sawdust on chitosan resulted in effective adsorption of both anionic and cationic dyes.

Keywords

EN

chitosan; chitosan beads; modified sawdust immobilised in chitosan; dye

Discipline

• CHEMISTRY: CHEMISTRY

• Publisher: Polish Chitin Society
• Journal: Progress on Chemistry and Application of Chitin and its Derivatives
• Year: 2022
• Volume: 27
• Pages: 79-91

Contributors

author

Urszula Filipkowska

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn

author

Tomasz Jóźwiak

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn

author

Magdalena Filipkowska

• 11-041 Olsztyn Poland

References

• [1] Anielak AM; (1995) Odbarwianie ścieków pofarbiarskich w procesie wspłóstrącania i sorpcji. Wydawnictwo Uczelniane Wyższej Szkoły Inżynierskiej, Koszalin
• [2] Pohorecki R; (2002) Problemy hydrodynamiczne w inżynierii bioreaktorów. Inżynieria i Aparatura Chemiczna, 3, 119-120.
• [3] Dziubiński M, Sowiński J; (2002) Współczynnik wnikania tlenu w reaktorze air – lift. Inżynieria i aparatura chemiczna, 3, 25-26.
• [4] Chisti MY, Moo-Young M; (1987) Pneumatically agitated bioreactor devices: effects of fluid height and flow area shape on hydrodynamic and mass transfer performance. In Moody GW, Baker PB (eds), Bioreactor and biotransformation. Springer, Dordrecht.
• [5] Momenzadeh H, Tehrani-Bagha AR, Khosravi A, Gharanjig K, Holmberg K; (2011) Reactive dye removal from wastewater using a chitosan nanodispersion. Desalination, 271, 225-230. DOI:10.1016/j.desal.2010.12.036
• [6] Guibal E, Roussy J; (2007) Coagulation and flocculation of dye-containing solutions using a biopolymer (Chitosan). React Funct Polym 67, 33-42. DOI:10.1016/j.reactfunctpolym.2006.08.008
• [7] Barron-Zambrano J, Szygula A, Ruiz M, Sastre AM, Guibal E; (2010) Biosorption of Reactive Black 5 from aqueous solutions by chitosan. Column studies. J Environ Manag 91, 2669-2675. DOI:10.1016/j.jenvman.2010.07.033
• [8] Szyguła A, Guibal E, Palacín MA, Ruiz M, Sastre AM; (2009) Removal of an anionic dye (Acid Blue 92) by coagulation-flocculation using chitosan. J Environ Manag 90, 2979-2986. DOI:10.1016/j.jenvman.2009.04.002
• [9] Dotto GL, Pinto LAA; (2011) Adsorption of food dyes onto chitosan: optimization process and kinetic. Carbohydr Polym 84, 231-238. DOI:10.1016/j.carbpol.2010.11.028
• [10] Akkaya G, Uzun İ, Güzel A; 2009 Adsorption of some highly toxic dyestuffs from aqueous solutions by chitin and its synthesized derivatives. Desalination 249, 1115-1123. DOI:10.1016/j.desal.2009.05.014
• [11] Hasan M, Ahmad AL, Hameed BH; (2008) Adsorption of reactive dye onto cross-linked chitosan/oil palm ash composite beads, Chem Eng J 136, 164-172. DOI:10.1016/J.CEJ.2007.03.038
• [12] Palma G, Freer J, Baeza J; (2003) Removal of metal ions by modified Pinus radiate bark and tannins from water solution. Water Res 37, 4974-4980 DOI:10.1016/j.watres.2003.08.008
• [13] Shukla A, Zhang Y-H, Dubey P, Margrave JL, Shukla SS; (2002) The role of sawdust in the removal of unwanted materials from water. J Hazard Mater B95, 137-152. DOI:10.1016/s0304-3894(02)00089-4
• [14] Özacar M, Şengil İA; (2005) A kinetic study of metal complex dye sorption onto pine sawdust. Process Biochem 40, 565-572. DOI:10.1016/j.procbio.2004.01.032
• [15] Garg VK, Ravi Kumar MNV, Gupta R; (2004) Removal of malachite green dye from aqueous solution by adsorption using agroindustries waste: a case study of Phosopis cineraria. Dyes Pigments 62, 1-10. DOI:10.1016/j.dyepig.2003.10.016
• [16] Baouab MHV, Gauthier R, Gauthier H, Rammah MEB; (2001) Cationized sawdust as ion exchange for anionic residual dyes. J Appl Polym Sci 82, 31-37. DOI:10.1016/j.carbpol.2012.05.005
• [17] Ho YS, McKay G; (1998) Sorption of dye from aqueous solution by peat. J Chem Eng 70, 115-124. DOI:10.1016/S0923-0467(98)00076-1
• [18] Garg VK, Gupta R, Yadav AB, Ravi Kumar MNV; (2003) Dye removal from aqueous solution by adsorption on treated sawdust. Bioresour Technol, 89, 121-124. DOI:10.1016/s0960-8524(03)00058-0
• [19] Batzias FA, Sidiras DK; (2004) Dye adsorption by calcium chloride treated beech sawdust in batch and fixed-bed systems. J Hazard Mater B114, 167-174. DOI:10.1016/j.jhazmat.2004.08.014
• [20] Witek-Krowiak A, Mitek M, Pokomeda K, Szafran RG, Modelski S; (2010) Biosorption of cationic dyes by beech sawdust ii. Effect of parameters on the process efficiency. Chem Process Eng 31, 421-432. DOI:10.1080/19443994.2012.749053
• [21] Dulman V, Cucu-Man SM; (2009) Sorption of some textile dye by beech wood sawdust. J Hazard Mater 162, 1457-1464. DOI:10.1016/j.jhazmat.2008.06.046
• [22] Gupta VK, Srivastava SK, Tyagi R; (2000) Design parameters for the treatment of phenolic wastes by carbon columns (obtained from fertilizer waste material). Water Res 34, 1543-1550. DOI:10.1016/S0043-1354(99)00322-X

• Document Type: article