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Number of results
2015 | 20 | 54-63

Article title

PERVAPORATIVE INVESTIGATION OF ETHYL ALCOHOL DEHYDRATION

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EN

Abstracts

EN
Pervaporative separation properties of crosslinked chitosan and alginate membrane on ethanol-water mixture at room temperature was studied. The influence of crosslinking agents on the separation properties were discussed. Selected crosslinking agents were affected differently on used polymer matrices. The better separation properties were obtained for membranes crosslinked by phosphoric (V) acid. The highest pervaporation separation index (309.6 kg/m2·h) and separation factor (52.6) were obtained for phosphoric (V) acid crosslinked alginate membranes, however, the greatest total flux (12.4 kg/m2·h) obtained for phosphoric acid crosslinked chitosan membranes

Contributors

  • 1Faculty of Chemistry, Silesian University of Technology ul. Akademicka 2A, 44-100 Gliwice, Poland
  • 1Faculty of Chemistry, Silesian University of Technology ul. Akademicka 2A, 44-100 Gliwice, Poland
author
  • 1Faculty of Chemistry, Silesian University of Technology ul. Akademicka 2A, 44-100 Gliwice, Poland
author
  • 1Faculty of Chemistry, Silesian University of Technology ul. Akademicka 2A, 44-100 Gliwice, Poland
  • 1Faculty of Chemistry, Silesian University of Technology ul. Akademicka 2A, 44-100 Gliwice, Poland
  • Faculty of Energy and Environmental Engineering, Silesian University of Technology, ul. Konarskiego 18, 44-100, Gliwice, Poland
  • 1Faculty of Chemistry, Silesian University of Technology ul. Akademicka 2A, 44-100 Gliwice, Poland

References

  • 1. Moon G.Y., Pal R., Huang R.Y.M.; (1999) Novel two-ply composite membranes of chitosan and sodium alginate for the pervaporation dehydration of isopropanol and ethanol. J. Membr. Sci. 156, 17-27.
  • 2. Lee Y.M., Nam S.Y., Woo D.J.; (1997) Pervaporation of ionically surface crosslinked chitosan composite membranes for water-alcohol mixtures, J. Membr. Sci. 133, 103-110. DOI: 10.1016/S0376-7388(97)00089-6
  • 3. Huang R.Y.M., Pal R., Moon G.Y.; (1999) Characteristics of sodium alginate membranes for the pervaporation dehydration of ethanol-water and isopropanol-water mixtures. J. Membr. Sci. 160. 101-113.
  • 4. Dudek G., Gnus M., Turczyn R., Strzelewicz A., Krasowska M.; (2014) Pervaporation with chitosan membranes containing iron oxide nanoparticles. Sep. Purif. Techn. 133, 8-15. DOI: 10.1016/j.seppur.2014.06.032
  • 5. Tan S.H., Ahmad A.L., Nawawi M.G.M., Hassan H.; (2002) Performance of chitosan membranes crosslinked with glutaraldehyde in pervaporation separation. ASEAN Journal for Science and Technology Development 19, 69.
  • 6. Kalyani S., Smitha B., Sridhar S., Krishnaiah A.; (2008) Pervaporation separation of ethanol – water mixtures through sodium alginate membranes. Desalination 229, 68-81. DOI: 10.1016/j.desal.2007.07.027
  • 7. Saraswathi M., Madhusudhan Rao K., Prabhakar M.N., Prasad C.V., Sudakar K., Naveen Kumar H.M.P., Prasad M., Chowdoji Rao K., Subha M.C.S.; (2011) Pervaporation studies of sodium alginate (SA)/dextrin blend membranes for separation of water and isopropanol mixture. Desalination 269, 177-183. DOI: 10.1016/j.desal.2010.10.059
  • 8. Kalyani S., Smitha B., Sridhar, A. Krishnaiah A.; (2006) Separation of ethanol-water mixtures by pervaporation using sodium alginate/poly(vinyl pyrrolidone) blend membrane crosslinked with phosphoric acid. Ind. Eng. Chem. Res. 45, 9088-9095. DOI: 10.1021/ie060085y
  • 9. Kopeć R., Meller M., Kujewski W. Kujawa J.; (2013) Polyamide-6 based pervaporation membranes for organic-organic separation, Separation and Purification Technology 110, 63-73. DOI: 10.1016/j.seppur.2013.03.007
  • 10. Chanachai A., Jiraratananon R., Uttapap D., Moon G.Y., Anderson W.A., Huang R.Y.M.; (2000) Pervaporation with chitosan/hydroxyethylcellulose (CS/HEC) blended membranes. J. Membr. Sci. 166, 271-280.
  • 11. Yeom C.K., Lee K.H.; (1997) Characterization of sodium alginate membrane crosslinked with glutaraldehyde in pervaporation separation. J. Appl. Polym. Sci. 67, 209-219. DOI: 10.1002/(SICI)1097-4628(19980110)67:2<209::AID-APP3>3.0.CO;2-Y
  • 12. Yeom C.K., Lee K.H.; (1997) Characterization of sodium alginate and poly(vinyl alcohol) blend membranes in pervaporation separation. J. Appl. Polym. Sci. 67, 949-959. DOI: 10.1002/(SICI)1097-4628(19980131)67:5<949::AID-APP20>3.0.CO;2-H
  • 13. Zhang W., Li G., Fang Y., Wang X.; (2007) Maleic anhydride surface-modyfication of crosslinked chitosan membrane and ist pervaporation performance. Journal of Membrane Science 295, 130-138.
  • 14. Sunitha S., Satyanarayana S.V., Sridhar S.; (2012) Phosphorylated chitosan membranes for the separation of ethanol-water mixtures by pervaporation. Carbohydr. Polym. 87, 1569-1574. DOI: 10.1016/j.carbpol.2011.09.054

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article

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bwmeta1.element.psjd-81c54a93-b779-45d1-aa27-a1bca11f6027
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