Preferences help
enabled [disable] Abstract
Number of results
2015 | 20 | 122-129
Article title


Title variants
Languages of publication
The aim of this work was to investigate the effect of different nanoparticles (TiO2 and organically modified montmorillonite MMT) on thermal stability of chitosan thin films (obtained by casting) and to compare with previously studied- CuO and Ag effect. Thermal degradation was carried out in air atmosphere at 140°C up to 100 hours. Various functional groups of chitosan have a different susceptibility to degradation. The influence of nanoparticles amount on degradation of selected structural groups of chitosan was calculated. It was proved, that elongation at break of chitosan sample and its nanocomposites with TiO2 and organically modified montmorillonite decrease rapidly after 20h of thermal degradation. Moreover, as is clear from FTIR studies, that TiO2 nanoparticles enhance the resistant of the -C-O-C- bond responsible for chain scission of chitosan due to thermal degradation. An opposite effect is observed in a case of MMT, where the chain scission of -C-O-C- bond is higher than for pure chitosan. Another effect of nanoparticles are observed in destruction of unstable amine group (-NH3 band at 1560 cm-1) and formation of the amide group (band at 1650 cm-1). In this case both nanoadditives accelerate the decomposition of amine group and the formation of amide group in higher extent in comparison to pure chitosan.
Physical description
  • Faculty of Process and Environmental Engineering, Lodz University of Technology, ul. Wólczańska 215, 90-924 Łódź, Poland
  • Faculty of Process and Environmental Engineering, Lodz University of Technology, ul. Wólczańska 215, 90-924 Łódź, Poland
  • 1. Kumar AP, Depan D, Tomer NS, Singh RP; (2009) Nanoscale particles for polymer degradation and stabilization—Trends and future perspective. Progress in Polym. Sci. 34, 479–515.
  • 2. Reddy MM, Vivekanandhana S, Misraa M; (2013) Biobased plastics and bionanocomposites: Current status and future opportunities. Progress in Polym. Sci., 38, 1653– 1689. DOI: 10.1016/j.progpolymsci.2013.05.006
  • 3. Nguyen QT, Baird DG, (2006) Preparation of Polymer–Clay Nanocomposites and Their Properties. Adv.Polym. Technol., 25, 270–285. DOI: 10.1002/adv.20079
  • 4. Farzana MH, Meenakshi S, (2014) Synergistic effect of chitosan and titanium dioxide on the removal of toxic dyes by the photodegradation technique. Ind. Eng. Chem. Res., 53, 55−63. DOI: 10.1021/ie402347g
  • 5. Mucha M, Pawlak A. (2002) Complex study on chitosan degradability Polimery, 7-8, 509-516.
  • 6. Mucha M, Pawlak A. Thermal Analysis of Chitosan and its Blends. Thermochimica Acta, 2005, 427, 69-76.
  • 7. Bialas S, M.Mucha M. (2013) Influence of nanosilver on thermal stability of chitosan. Progress on Chemistry and Applications of Chitin and its Derivatives, 85-93.
  • 8. Mucha M, Ksiazek S, Kaczmarek H. (2014) Activation energy of copper-induced thermal degradation of chitosan functional groups. J. Polym. Eng. (in press). DOI: 10.1515/polyeng-2014-0157
  • 9. Mucha M, S.Bialas S. (2013) Thermal and photochemical stability of chitosan doped by nanosilver. J. Chitin Chitosan Sci. 1, 235-239.
  • 10. Damarger-Andre S, Domard A. (1994) Chitosan carboxylic acid salts in solution and in the solid state. Carbohydrate Polymers, 23, 211-219.
  • 11. Higazy A, Hashem M, ElShafei A, Nihal Shaker N, Marwa Abdel Hady. (2010) Development of antimicrobial jute packaging using chitosan and chitosan–metal complex. Carbohydrate Polymers, 79, 867-874.
Document Type
Publication order reference
YADDA identifier
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.