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2021 | 160 | 158-171
Article title

Mechanical Properties, Morphology and Elemental Composition of Composites Produced from Acrylonitrile-Butadiene-Styrene Thermoplastics Incorporated with Cow Horn

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The aim of this research is to develop environmentally friendly, lightweight composites using cow horn, as filler in Acrylonitrile-Butadiene-Styrene (ABS) polymers; to determine the tensile strength and tensile modulus properties of the cow horn-residue polymer composite, to find if there is any new improvement over the properties of the starting polymer and to determine the morphology and elemental composition of the composites. Cow horn was collected from the surroundings of Ekwulumili in Nnewi-South L.G.A and Nnewi-North both in Anambra State, Eastern Nigeria where they have been dumped after usage. The research was carried-out at JUNENG NIG LIMITED Enugu, Civil Engineering Department Laboratory University of Nigeria and Chemical Engineering Department Laboratory Ahmadu Bello University (ABU), Nigeria; between May 2016 and August 2018. The cow-horn were grand into power and incorporated into the virgin thermoplastic polymers as filler at varied levels of 3%, 6%, 9%, 12% and 15%. The virgin thermoplastic polymers were used as the Control in the study. The tensile strength and modulus of elasticity property of the composites produced were determined using American standard for Testing and Materials (ASTM), Standard Testing Methods; Scanning Electron Microscopy (SEM) was used to determine morphology while Energy Dispersive Spectroscopy (EDS) was used to determine the elemental composition of the composites. The results generally showed significant improvements in tensile strength and tensile modulus of the blend ABS cow horn filler composites which were influenced by the amount of filler in the composites. ABS matrix loaded with 3% MoE of 516.72 MPa (Mega Pascal), ABS 6% MoE of 335.73 MPa, ABS matrix loaded with 9% of cow horn had MoE of 463.30 MPa, ABS matrix loaded with 12% of cow horn had MoE value of 209.24 MPa and ABS matrix loaded with 15% of cow horn had MoE of 236.36 MPa. MoE of 160.68 MPa for pure ABS matrix. The values obtained for tensile strength are 15.62 MPa, 9.05 MPa, 13.98 MPa, 10.69 MPa, 5.76 MPa and 6.58 MPa for 3%, 6%, 9%, 12%, 15% of cow horn filler and pure ABS matrix respectively. Scanning electron microscopy (SEM) was carried out on the samples using imageJ software to estimate the average particle size of the polymer cow horn. The micrograph reveals some agglomeration bulk and voids at the edges of the particles of the filler material with the polymer. The elemental compositional analysis, using Energy Dispersive Spectroscopy (EDS) has sample contains C and N as a major element present and others as trace; Fe, Na, Ag, Cu, Ti, Al, Mg, P, Zn, Si and S. This study has proven that combinations of lost-cost cow horn -residue filler reinforced with thermoplastic polymer composites are gaining significant roles in building and automobile industries, and other consumer applications. Also, would serve as a means of turning waste to wealth by utilizing agro-waste products in developing low cost polymer composites to serve a number of interesting applications.
Physical description
  • Industrial Chemistry Department Federal university lokoja, Kogi State, Nigeria
  • Industrial Chemistry Department Nnamdi Azikiwe University Awka, Anambra State, Nigeria
  • Department of Geology, Chukwuemeka Odumegwu Ojukwu University, Anambra State, Nigeria
  • Department of Chemistry, Chukwuemeka Odumegwu Ojukwu University, Anambra State, Nigeria
  • Department of Chemistry, Chukwuemeka Odumegwu Ojukwu University, Anambra State, Nigeria
  • [1] Cheng, Q., Wang, J., Wen, J., Liu, C., Jiang, K., Li, Q. and Fan, S., Carbon nanotube/epoxy composites fabricated by resin transfer moulding. Carbon 48(1) (2010) 260-266
  • [2] Choi, N. W., Mori, I. and Ohama Y., Development of Rice Husks Plastic Composite for Building Materials, Journal of Waste Management, 26(2) (2006) 189-194
  • [3] Crespo, J. E., Sánchez, L. D., García and López J., “Study of the Mechanical and Morphological Properties of Plasticized PVC Composites Containing Rice Husk Fillers,” Journal of Reinforced Plastics and Composites, 27 (3) (2008) 229-243
  • [4] Ewansila, C. J., Ebhoaye, J. E., Asia, I. O., Ekebafe, L. O. and Ehigie, C. Proximate and minerial composition of coconut (Cocos Nucifera) shell. International Journal of Pure and Applied Science and Technology, 13(1) (2012) 53-56
  • [5] Faruk, O., Bledzki, A.K., Fink, H-P, Sain, M., ’Biocomposites reinforced with natural fibers: Prog Polym Sci 37 (2010) 1552-1596
  • [6] Fono – Toma, R. S. and Koya, O. A., Characterization of pulverized palm kernel shell for sustainable waste diversification. International Journal of Scientific and Engineering Research, 4(4) (2013) 6-10
  • [7] Iftekhar, A. and Prakash, A. M., Mechanical Properties of Fly Ash Filled High Density Polyethylene,” Journal of Minerals & Minerals Characterization & Engineering, 9 (3) (2010) 183-198
  • [8] Ikumapayi, O. M. and Akinlabi, E. T., Composition, characteristics and socioeconomic benefits of palm kernel shell exploitation: an overview. Journal of Environmental Science and Technology, 11 (2018) 220-232
  • [9] Leman, A. S., Shahidan, S., Senin, M. S. and Hannan, N. I. R. R. A preliminary study or chemical and physical properties of coconut shell powder as a filler in concrete. Conference series: Material Science and Engineering, 160, 012059 (2016) 1-7
  • [10] Ofor H.O. Mechanical Properties, Morphology and Elemental Composition of composites produced from Thermoplastic Polymers Filled with Egg Shell. International Research Journal of Pure and Applied Chemistry, 22(1) (2021) 59-78
  • [11] Ofor, H. O. (2021). Physico-Mechanical Properties of Composites Produced from Thermoplastic Polymers Filled with Egg Shell. Chemical Science International Journal, 30(1), 28-45.
  • [12] Ofor H.O and Ojiako E.N. The Effect of Cow Horn as Filler on the Physico-Mechanical Property in Polymeric Matrices Composite”. Journal of Basic Physical Research. 9 (1) (2019): 81-90.
  • [13] Ofor H.O and Ojiako E.N. The Effect of Egg Shell as Filler on Creep Mechanical Property in Thermoplastic Polymer Matrices Composite. ANACHEM Journal 9 (1) (2019) 1630-1644
  • [14] Ofor H.O and Ojiako E.N. The Effect of Palm Kernel Shell as Filler on the Physico-Mechanical Property in Polymeric Matrices Composite”. Journal of Basic Physical Research 9 (1) (2019) 71-80
  • [15] Ojiako E.N, Ofor H.O and Nwadiogwu J.O. The Effect of Palm Kernel Shell as Filler on the Physico-Mechanical Property in Polymeric Matrices Composite. COOU Journal of Physical Sciences 2 (2) (2019) 101-128
  • [16] Ricky Dave T. Mercado, Romnick M. Ureta, Reynan Jay D. Templo, The Potential of Selected Agricultural Wastes Fibers as Acoustic Absorber and Thermal Insulator Based on their Surface Morphology via Scanning Electron Microscopy. World News of Natural Sciences 20 (2018) 129-147
  • [17] Ritesh D. Bhatt, Jignesh P. Patel, Parsotam H. Parsania, Potential comparison of montmorillonite filled and unfilled epoxy methacrylate of bisphenol-C-glass/ jute/treated jute and hybrid composites. World Scientific News 158 (2021) 227-246
  • [18] Sapuan, SM, Pua F., El-Shekeil Y. and AL-Oqla FM. Mechanical properties of soil buried kenaf fibre reinforced thermoplastic polyurethane composites. Mater Des 50 (2013) 467–470
  • [19] Sarikanat, M. The influence of oligomeric siloxane concentration on the mechanical behaviours of alkalized jute/modified epoxy composites. J Reinf Plast Compos 29(6) (2010) 807–817
  • [20] Simone, M., Rosa, L., Evelise, F. S., Carlos, A. F. and Sonia M. B. N. Studies on the Properties of Rice Husk Filled Polypropylene Composites—Effect of Maleate Polypropylene. Journal of Material Science, 12 (3) (2009) 333-338
  • [21] Thakur, V., Singha, A. and Thakur, M. Biopolymers based green composites: Mechanical, thermal and physico-chemical characterization. J Polym Environ 20(2) (2012) 412–421
  • [22] Timothy, T., Ryan, M., Lisa, C., Christiana, W., and Caroline, B. Development and Characteristics of New Materials Base on Plastic Waste and Agro Fibre. Business Media, 43(26) (2008) 4057-4068
  • [23] UNCEP, Governing Council Ministerial Environment Forum, during Its 25th Session in February, 2009.
  • [24] Venkateshwaran, N., Elayaperumal, A., Alavudeen, A. and Thiruchitrambalam, M. Review of Artificial Neural Network and Taguchi Application in Polymer Matrix Composites. Journal of Review Advance Material Science, 29 (2011) 100
  • [25] Yusriah, L., Sapuan, S., Zainudin, E.S. and Mariatti, M., Characterization of physical, mechanical, thermal and morphological properties of agro-waste betel nut (Areca catechu) husk fibre. J Clean Prod 72 (2014) 174–180
  • [26] Ümit Çevik and Menderes Kam. A review study on Mechanical Properties of Obtained Products by FDM Method and Metal/Polymer Composite Filament Production. Journal of Nanomaterials, 2020.
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